[Cu(I)(N-ethyl-N-[2-(2-pyridyl)ethyl]-α,α-dideuterio-benzylamine)(acetonitrile)]PF6

Base Information

• Chemical Name: [Cu(I)(N-ethyl-N-[2-(2-pyridyl)ethyl]-α,α-dideuterio-benzylamine)(acetonitrile)]PF6
• CAS No.: 442852-75-7
• Molecular Formula: C₁₈H₂₃CuN₃*F₆P
• Molecular Weight: 491.895
• Mol file: 442852-75-7.mol

Synonyms:[Cu(I)(N-ethyl-N-[2-(2-pyridyl)ethyl]-α,α-dideuterio-benzylamine)(acetonitrile)]PF6

Chemical Property of [Cu(I)(N-ethyl-N-[2-(2-pyridyl)ethyl]-α,α-dideuterio-benzylamine)(acetonitrile)]PF6

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Cu(I)(N-ethyl-N-[2-(2-pyridyl)ethyl]-α,α-dideuterio-benzylamine)(acetonitrile)]PF6

There total 1 articles about [Cu(I)(N-ethyl-N-[2-(2-pyridyl)ethyl]-α,α-dideuterio-benzylamine)(acetonitrile)]PF6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tetrakis(actonitrile)copper(I) hexafluorophosphate (64443-05-6) + N-ethyl-N-[2-(2-pyridyl)ethyl]-α,α-dideuteriobenzyl amine → [Cu(I)(N-ethyl-N-[2-(2-pyridyl)ethyl]-α,α-dideuterio-benzylamine)(acetonitrile)]PF6 (442852-75-7)

Guidance literature:

In tetrahydrofuran; under anaerobic conditions; ligand (1 equiv.) treated with Cu complex inTHF; stirred at room temp. for 15 min; filtered; ether added to filtrate; pptd. by standing for several min; supernatant removed by decantation; solid washed with ether; dried;

DOI:10.1021/ja026047x

Reference yield: 83.0%

[Cu(I)(N-ethyl-N-[2-(2-pyridyl)ethyl]-α,α-dideuterio-benzylamine)(acetonitrile)]PF6 (442852-75-7) + triphenylphosphine (603-35-0) → [Cu(I)(N-(CD2C6H5)-N-ethyl-2-(2-pyridyl)ethylamine)(triphenylphosphine)]PF6 (442852-70-2)

Guidance literature:

In tetrahydrofuran; under anaerobic conditions; THF soln. of PPh3 (2 equiv.) added to suspn.of Cu complex in THF; stirred at room temp. for 5 min; filtered; filtrate added dropwise to ether; ppt. isolated by decantation; washed with ether; elem. anal.;

DOI:10.1021/ja026047x

Reference yield:

[Cu(I)(N-ethyl-N-[2-(2-pyridyl)ethyl]-α,α-dideuterio-benzylamine)(acetonitrile)]PF6 (442852-75-7) + oxygen (80937-33-3) → bis(N-ethyl-N-[2-(2-pyridyl)ethyl]-α,α-dideuterio-benzylamine)bis(μ-oxo)dicopper(III)(2+) (355005-87-7)

Guidance literature:

In acetone; dry O2 introduced into acetone soln. of Cu complex at -94°C; not isolated;

DOI:10.1021/ja015721s

upstream raw materials:

tetrakis(actonitrile)copper(I) hexafluorophosphate

Downstream raw materials:

bis(N-ethyl-N-[2-(2-pyridyl)ethyl]-α,α-dideuterio-benzylamine)bis(μ-oxo)dicopper(III)(2+)

[Cu(I)(N-(CD₂C₆H₅)-N-ethyl-2-(2-pyridyl)ethylamine)(triphenylphosphine)]PF₆