[1,2-bis(dimethylphosphino)ethane](chloro)(pentafluorophenyl)platinum(II)

Base Information

Chemical Name:[1,2-bis(dimethylphosphino)ethane](chloro)(pentafluorophenyl)platinum(II)
CAS No.:777857-69-9
Molecular Formula:C₁₂H₁₆ClF₅P₂Pt
Molecular Weight:547.732
Hs Code.:

Synonyms:[1,2-bis(dimethylphosphino)ethane](chloro)(pentafluorophenyl)platinum(II)

Suppliers and Price of [1,2-bis(dimethylphosphino)ethane](chloro)(pentafluorophenyl)platinum(II)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [1,2-bis(dimethylphosphino)ethane](chloro)(pentafluorophenyl)platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [1,2-bis(dimethylphosphino)ethane](chloro)(pentafluorophenyl)platinum(II)

There total 1 articles about [1,2-bis(dimethylphosphino)ethane](chloro)(pentafluorophenyl)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: {platinum(II)(μ-chloride)(pentafluorophenyl)(tetrahydrothiophene)}2

: 23936-60-9
1,2-bis(dimethylphosphanyl)ethane

: 777857-69-9
[1,2-bis(dimethylphosphino)ethane](chloro)(pentafluorophenyl)platinum(II)

Guidance literature:: In chloroform; toluene; under N2 atm. to soln. (Pt2(C6F5)2(tht)2(μ-Cl)2) in CHCl3 soln. dmpe in toluene was added, heated at reflux for 1 h and stirred overnight at room temp.; solvent was removed in vacuo, residue was recrystd. from CHCl3-hexane; elem. anal.;
DOI:10.1039/b406602b

Reference yield: 61.0%

: 777857-69-9
[1,2-bis(dimethylphosphino)ethane](chloro)(pentafluorophenyl)platinum(II)

: 777857-78-0
[1,2-bis(dimethylphosphino)ethane]bis(pentafluorophenyl)platinum(II)

Guidance literature:: With AgOTf; In chloroform; under N2 atm. to suspn. AgOTf in CHCl3 soln. ((dmpe)Pt(C6F5)Cl) in CHCl3was added and stirred at room temp. for 2 h, filtered and stirred for 3 weeks at room temp.; soln. was filtered, solvent was removed in vacuo, residue was recrystd from CH2Cl2-hexane; elem. anal.;
DOI:10.1039/b406602b

Reference yield: 59.0%

: 16940-66-2
sodium tetrahydroborate

: 777857-69-9
[1,2-bis(dimethylphosphino)ethane](chloro)(pentafluorophenyl)platinum(II)

: 777857-81-5
[1,2-bis(dimethylphosphino)ethane](hydrido)(pentafluorophenyl)platinum(II)

Guidance literature:: In tetrahydrofuran; under N2 atm. to suspn ((dmpe)Pt(C6F5)Cl) in THF NaBH4 was added and heated at reflux for 12 h; react. mixt. was cooled to room temp., solvent was removed in vacuo, residue was extd. with ether, solvent was removed in vacuo; elem. anal.;
DOI:10.1039/b406602b