23936-60-9 Usage
Chemical Properties
Colorless to light yellow liqui
Uses
1,2-Bis(dimethylphosphino)ethane (dmpe) may be employed as ligand in the preparation of cis-arylmethyl(dmpe) nickel(II) complexes.
General Description
1,2-Bis(dimethylphosphino)ethane (dmpe) is a polydentate phosphine ligand. Synthesis of 1,2-bis(dimethylphosphino)ethane has been reported. It reacts with ZrCl2 to afford ZrCl4(dmpe)2 complexes.
Check Digit Verification of cas no
The CAS Registry Mumber 23936-60-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,3,9,3 and 6 respectively; the second part has 2 digits, 6 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 23936-60:
(7*2)+(6*3)+(5*9)+(4*3)+(3*6)+(2*6)+(1*0)=119
119 % 10 = 9
So 23936-60-9 is a valid CAS Registry Number.
InChI:InChI=1/C6H16P2/c1-7(2)5-6-8(3)4/h5-6H2,1-4H3
23936-60-9Relevant articles and documents
Dimethyl(N,N,N′,N′-tetramethylethanediamine)palladium(II) and dimethyl[1,2-bis(dimethylphosphino)ethane]palladium(II): Syntheses, X-ray crystal structures, and thermolysis, oxidative-addition, and ligand-exchange reactions
De Graaf, Wim,Boersma, Jaap,Smeets, Wilberth J. J.,Spek, Anthony L.,Van Koten, Gerard
, p. 2907 - 2917 (2008/10/08)
PdMe2(tmeda) (2a) (tmeda = N,N,N′,N′-tetramethylethanediamine) has been prepared and characterized by means of NMR spectroscopy and X-ray crystallography. Crystals of PdMe2(tmeda) are monoclinic, space group P21/n, with un
