C₂₆H₃₆N₄O₄SSi

Base Information

• Chemical Name: C₂₆H₃₆N₄O₄SSi
• CAS No.: 1246512-85-5
• Molecular Formula: C₂₆H₃₆N₄O₄SSi
• Molecular Weight: 528.748
• Mol file: 1246512-85-5.mol

Synonyms:C₂₆H₃₆N₄O₄SSi

Chemical Property of C₂₆H₃₆N₄O₄SSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₆H₃₆N₄O₄SSi

There total 17 articles about C₂₆H₃₆N₄O₄SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

C25H34N4O4SSi + methyl iodide (74-88-4) → C26H36N4O4SSi (1246512-85-5)

Guidance literature:

With potassium carbonate; In tetrahydrofuran; at 50 ℃; for 3h;

DOI:10.1002/asia.201000213

Reference yield:

C16H22N2O3Si (1169875-30-2) → C26H36N4O4SSi (1246512-85-5)

Guidance literature:

Multi-step reaction with 10 steps

1: sodium tetrahydroborate; cerium(III) chloride

2: pyridine

3: hydrogen fluoride; triethylamine

4: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 2 h / 0 - 25 °C

5: potassium carbonate / methanol

6: sodium hydride / tetrahydrofuran

7: diisobutylaluminium hydride

8: hydrogen

9: methanesulfonyl chloride; triethylamine / dichloromethane / 1.5 h / 0 - 20 °C / Inert atmosphere

10: potassium carbonate / tetrahydrofuran / 3 h / 50 °C

With pyridine; sodium tetrahydroborate; cerium(III) chloride; hydrogen fluoride; hydrogen; sodium hydride; diisobutylaluminium hydride; potassium carbonate; methanesulfonyl chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; In tetrahydrofuran; methanol; dichloromethane; 4: Overman rearrangement;

DOI:10.1002/asia.201000213

Reference yield:

C16H24N2O3Si → C26H36N4O4SSi (1246512-85-5)

Guidance literature:

Multi-step reaction with 9 steps

1: pyridine

2: hydrogen fluoride; triethylamine

3: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 2 h / 0 - 25 °C

4: potassium carbonate / methanol

5: sodium hydride / tetrahydrofuran

6: diisobutylaluminium hydride

7: hydrogen

8: methanesulfonyl chloride; triethylamine / dichloromethane / 1.5 h / 0 - 20 °C / Inert atmosphere

9: potassium carbonate / tetrahydrofuran / 3 h / 50 °C

With pyridine; hydrogen fluoride; hydrogen; sodium hydride; diisobutylaluminium hydride; potassium carbonate; methanesulfonyl chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; In tetrahydrofuran; methanol; dichloromethane; 3: Overman rearrangement;

DOI:10.1002/asia.201000213

upstream raw materials:

C₁₆H₂₄N₂O₃Si

C₁₆H₂₄N₂O₄Si

C₁₆H₂₂N₂O₃Si

C₁₂H₁₂N₂O₄

Downstream raw materials:

C₁₉H₁₈N₄O₄

C₂₀H₂₀N₄O₃S

C₁₉H₁₈N₄O₄