5-O-benzoyl-2-deoxy-2-(p-thiotolyl)-α-D-arabinofuranosyl azide

Base Information

• Chemical Name: 5-O-benzoyl-2-deoxy-2-(p-thiotolyl)-α-D-arabinofuranosyl azide
• CAS No.: 1185748-22-4
• Molecular Formula: C₁₉H₁₉N₃O₄S
• Molecular Weight: 385.444
• Mol file: 1185748-22-4.mol

Synonyms:5-O-benzoyl-2-deoxy-2-(p-thiotolyl)-α-D-arabinofuranosyl azide

Chemical Property of 5-O-benzoyl-2-deoxy-2-(p-thiotolyl)-α-D-arabinofuranosyl azide

Chemical Property:

Purity/Quality:

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Technology Process of 5-O-benzoyl-2-deoxy-2-(p-thiotolyl)-α-D-arabinofuranosyl azide

There total 2 articles about 5-O-benzoyl-2-deoxy-2-(p-thiotolyl)-α-D-arabinofuranosyl azide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

p-tolyl 2,3-anhydro-5-O-benzoyl-1-thio-β-D-lyxofuranoside (329360-43-2) → 5-O-benzoyl-2-deoxy-2-(p-thiotolyl)-α-D-arabinofuranosyl azide (1185748-22-4)

Guidance literature:

With trimethylsilylazide; boron trifluoride diethyl etherate; In dichloromethane; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1016/j.tet.2009.06.008

Reference yield: 49.0%

p-tolyl 2,3-anhydro-5-O-benzoyl-1-thio-β-D-lyxofuranoside (329360-43-2) → 5-O-benzoyl-2-deoxy-2-(p-thiotolyl)-α-D-arabinofuranosyl azide (1185748-22-4) + 5-O-benzoyl-2-deoxy-2-(p-thiotolyl)-3-O-(5-O-benzoyl-2-deoxy-2-(p-thiotolyl)-α-D-arabino-furanosyl)-α-D-arabinofuranosyl azide (1185748-23-5)

Guidance literature:

With trimethylsilylazide; boron trifluoride diethyl etherate; In dichloromethane; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1016/j.tet.2009.06.008

upstream raw materials:

p-tolyl 2,3-anhydro-5-O-benzoyl-1-thio-β-D-lyxofuranoside