{4-[8-(tert-butyldiphenylsilanyloxy)-3,7-dimethylocta-2,6-dienyl]-3,5-bis(methoxymethoxy)phenyl}methanol

Base Information

Chemical Name:{4-[8-(tert-butyldiphenylsilanyloxy)-3,7-dimethylocta-2,6-dienyl]-3,5-bis(methoxymethoxy)phenyl}methanol
CAS No.:865761-91-7
Molecular Formula:C₃₇H₅₀O₆Si
Molecular Weight:618.886
Hs Code.:

Synonyms:{4-[8-(tert-butyldiphenylsilanyloxy)-3,7-dimethylocta-2,6-dienyl]-3,5-bis(methoxymethoxy)phenyl}methanol

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Chemical Property of {4-[8-(tert-butyldiphenylsilanyloxy)-3,7-dimethylocta-2,6-dienyl]-3,5-bis(methoxymethoxy)phenyl}methanol

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Technology Process of {4-[8-(tert-butyldiphenylsilanyloxy)-3,7-dimethylocta-2,6-dienyl]-3,5-bis(methoxymethoxy)phenyl}methanol

There total 2 articles about {4-[8-(tert-butyldiphenylsilanyloxy)-3,7-dimethylocta-2,6-dienyl]-3,5-bis(methoxymethoxy)phenyl}methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 881075-33-8
(2E,6E)-8-(tert-butyldiphenylsilyloxy)geranyl bromide

: 76280-60-9
[3,5-bis(methoxymethoxy)phenyl]methanol

: 865761-91-7
{4-[8-(tert-butyldiphenylsilanyloxy)-3,7-dimethylocta-2,6-dienyl]-3,5-bis(methoxymethoxy)phenyl}methanol

Guidance literature:: [3,5-bis(methoxymethoxy)phenyl]methanol; With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; potassium hydride; copper(I) bromide dimethylsulfide complex; In tetrahydrofuran; hexane; at -20 ℃; for 1h;

(2E,6E)-8-(tert-butyldiphenylsilyloxy)geranyl bromide; In tetrahydrofuran; hexane; at -20 ℃; for 2h;
DOI:10.1016/j.bmc.2005.10.025

Reference yield:

: 127969-90-8
(2E,6E)-8-((tert-butyldiphenylsilyl)oxy)-3,7-dimethylocta-2,6-dien-1-ol

: 865761-91-7
{4-[8-(tert-butyldiphenylsilanyloxy)-3,7-dimethylocta-2,6-dienyl]-3,5-bis(methoxymethoxy)phenyl}methanol

Guidance literature:: Multi-step reaction with 2 steps

1.1: PBr₃ / diethyl ether / 7 h / 0 °C

2.1: KH; TMEDA; n-BuLi / CuBr*Me₂S / tetrahydrofuran; hexane / 1 h / -20 °C

2.2: 341 g / tetrahydrofuran; hexane / 2 h / -20 °C

With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; phosphorus tribromide; potassium hydride; copper(I) bromide dimethylsulfide complex; In tetrahydrofuran; diethyl ether; hexane;
DOI:10.1016/j.bmc.2005.10.025