potassium tetracarbonylcobaltate

Base Information

Chemical Name:potassium tetracarbonylcobaltate
CAS No.:14878-26-3
Molecular Formula:C₄CoO₄*K
Molecular Weight:210.133
Hs Code.:

Synonyms:potassium tetracarbonylcobaltate

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Chemical Property of potassium tetracarbonylcobaltate

Chemical Property:

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Technology Process of potassium tetracarbonylcobaltate

There total 7 articles about potassium tetracarbonylcobaltate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 113109-37-8
PdPtCo₂(CO)7(dppm)2

: 14878-26-3
potassium tetracarbonylcobaltate

: 113132-12-0
PdPtCoI(CO)3(dppm)2

Guidance literature:: With potassium iodide; In water; acetone; A soln. of KI in a mixt. of acetone and water was added to a stirred soln. of PdPtCo2(CO)7(dppm)2 in acetone. The dark green soln. immediately turned red. Stirred for 3 h.; The solvents were evapd. in vac.; The red solid residue was washed with water to remove K{Co(CO)4} and the excess of KI. Extn. with CH2Cl2 gave a red soln. After addn. of n-hexane, crystals were obtained at -20°C. Elem.anal.;

Reference yield:

: 2K⁽¹⁺⁾*Co₄Ni₂^(2-)*14CO*6H₂O=K₂{Co₄Ni₂(CO)14}*6H₂O

: 13462-90-3
nickel(II) iodide

: 14878-26-3
potassium tetracarbonylcobaltate

: 13463-39-3,71564-36-8
tetracarbonyl nickel

: cobalt(II) iodide

Guidance literature:: With iodine; In tetrahydrofuran;
DOI:10.1016/S0010-8545(00)80045-4

Reference yield:

: 113109-37-8
PdPtCo₂(CO)7(dppm)2

: 14878-26-3
potassium tetracarbonylcobaltate

: 113132-11-9
PdPtCoCl(CO)3(dppm)2

Guidance literature:: With potassium chloride; In water; acetone; Addn. of a large excess of KCl in H2O was added to suspension of PdPtCo7(dppm)2 in acetone.; Mixt. not separated; detection by IR;;