methyl 4,6'-O-(1,3-xylylene)-(2,3,4-tri-O-benzyl-β-D-glucopyranosyl)-(1'->3)-2,6-di-O-benzyl-α-D-galactopyranoside

Base Information

Chemical Name:methyl 4,6'-O-(1,3-xylylene)-(2,3,4-tri-O-benzyl-β-D-glucopyranosyl)-(1'->3)-2,6-di-O-benzyl-α-D-galactopyranoside
CAS No.:241471-01-2
Molecular Formula:C₅₆H₆₀O₁₁
Molecular Weight:909.086
Hs Code.:

Synonyms:methyl 4,6'-O-(1,3-xylylene)-(2,3,4-tri-O-benzyl-β-D-glucopyranosyl)-(1'->3)-2,6-di-O-benzyl-α-D-galactopyranoside

Suppliers and Price of methyl 4,6'-O-(1,3-xylylene)-(2,3,4-tri-O-benzyl-β-D-glucopyranosyl)-(1'->3)-2,6-di-O-benzyl-α-D-galactopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 4,6'-O-(1,3-xylylene)-(2,3,4-tri-O-benzyl-β-D-glucopyranosyl)-(1'->3)-2,6-di-O-benzyl-α-D-galactopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 4,6'-O-(1,3-xylylene)-(2,3,4-tri-O-benzyl-β-D-glucopyranosyl)-(1'->3)-2,6-di-O-benzyl-α-D-galactopyranoside

There total 7 articles about methyl 4,6'-O-(1,3-xylylene)-(2,3,4-tri-O-benzyl-β-D-glucopyranosyl)-(1'->3)-2,6-di-O-benzyl-α-D-galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 241471-00-1
ethyl 6-O-[3-(methyl 2,6-di-O-benzyl-α-D-galactopyranoside-4-yloxymethyl)-benzyl]-2,3,4-tri-O-benzyl-1-thio-β-D-glucopyranoside

: 241471-01-2
methyl 4,6'-O-(1,3-xylylene)-(2,3,4-tri-O-benzyl-β-D-glucopyranosyl)-(1'->3)-2,6-di-O-benzyl-α-D-galactopyranoside

Guidance literature:: With N-iodo-succinimide; trifluorormethanesulfonic acid; In dichloromethane; for 0.5h;
DOI:10.1021/jo990132e

Reference yield:

: 53685-11-3
(2R,3R,4S,5R,6S)-5-Benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3,4-diol

: 241471-01-2
methyl 4,6'-O-(1,3-xylylene)-(2,3,4-tri-O-benzyl-β-D-glucopyranosyl)-(1'->3)-2,6-di-O-benzyl-α-D-galactopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1.1: dibutyltin oxide / toluene / 5 h / Heating

1.2: 72 percent / tetrabutylammonium iodide / toluene / 1 h / 90 °C

2.1: 61 percent / sodium hydride / dimethylformamide / 0 - 20 °C

3.1: 90 percent / 4,5-dichloro-3,6-dioxo-1,4-cyclohexadiene-1,2-dicarbonitrile / CH₂Cl₂; H₂O / 4 h / 20 °C

4.1: 84 percent / trifluoromethanesulfonic acid; N-iodosuccinimide / CH₂Cl₂ / 0.5 h

With N-iodo-succinimide; trifluorormethanesulfonic acid; sodium hydride; di(n-butyl)tin oxide; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water; N,N-dimethyl-formamide; toluene; 1.1: Substitution / 1.2: Alkylation / 2.1: Alkylation / 3.1: Elimination / 4.1: Cyclization;
DOI:10.1021/jo990132e

Reference yield:

: 39483-51-7,119645-03-3,128850-50-0,126461-54-9
ethyl 2,3,4-tri-O-benzyl-1-thio-β-D-glucopyranoside

: 241471-01-2
methyl 4,6'-O-(1,3-xylylene)-(2,3,4-tri-O-benzyl-β-D-glucopyranosyl)-(1'->3)-2,6-di-O-benzyl-α-D-galactopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 41 percent / 15-crown-5; sodium hydride / CH₂Cl₂ / 8 h / -17 °C

2: 61 percent / sodium hydride / dimethylformamide / 0 - 20 °C

3: 90 percent / 4,5-dichloro-3,6-dioxo-1,4-cyclohexadiene-1,2-dicarbonitrile / CH₂Cl₂; H₂O / 4 h / 20 °C

4: 84 percent / trifluoromethanesulfonic acid; N-iodosuccinimide / CH₂Cl₂ / 0.5 h

With N-iodo-succinimide; 15-crown-5; trifluorormethanesulfonic acid; sodium hydride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water; N,N-dimethyl-formamide; 1: Alkylation / 2: Alkylation / 3: Elimination / 4: Cyclization;
DOI:10.1021/jo990132e