tert-Butyl-dimethyl-{4-[(3E,5E,7E)-10-(tetrahydro-pyran-2-yloxy)-deca-3,5,7-trienyl]-phenoxy}-silane

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Chemical Name:tert-Butyl-dimethyl-{4-[(3E,5E,7E)-10-(tetrahydro-pyran-2-yloxy)-deca-3,5,7-trienyl]-phenoxy}-silane
CAS No.:287198-97-4
Molecular Formula:C₂₇H₄₂O₃Si
Molecular Weight:442.714
Hs Code.:

Synonyms:tert-Butyl-dimethyl-{4-[(3E,5E,7E)-10-(tetrahydro-pyran-2-yloxy)-deca-3,5,7-trienyl]-phenoxy}-silane

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Chemical Property of tert-Butyl-dimethyl-{4-[(3E,5E,7E)-10-(tetrahydro-pyran-2-yloxy)-deca-3,5,7-trienyl]-phenoxy}-silane

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Technology Process of tert-Butyl-dimethyl-{4-[(3E,5E,7E)-10-(tetrahydro-pyran-2-yloxy)-deca-3,5,7-trienyl]-phenoxy}-silane

There total 7 articles about tert-Butyl-dimethyl-{4-[(3E,5E,7E)-10-(tetrahydro-pyran-2-yloxy)-deca-3,5,7-trienyl]-phenoxy}-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 107148-48-1
(E)-tetrahydro-2-<(3-hexen-5-ynyl)oxy>-2H-pyran

: 287198-93-0
tert-butyl-[4-(4-iodo-but-3-enyl)-phenoxy]-dimethyl-silane

: 287198-97-4
tert-Butyl-dimethyl-{4-[(3E,5E,7E)-10-(tetrahydro-pyran-2-yloxy)-deca-3,5,7-trienyl]-phenoxy}-silane

Guidance literature:: (E)-tetrahydro-2-<(3-hexen-5-ynyl)oxy>-2H-pyran; With Bu₃SnCu(CN)Li; In tetrahydrofuran; at -40 ℃;

tert-butyl-[4-(4-iodo-but-3-enyl)-phenoxy]-dimethyl-silane; dichloro bis(acetonitrile) palladium(II); In N,N-dimethyl-formamide; at 20 ℃; for 0.5h;
DOI:10.1016/S0040-4039(00)00532-3

Reference yield:

: 40365-61-5
2-(but-3-yn-1-yloxy)tetrahydropyran

: 287198-97-4
tert-Butyl-dimethyl-{4-[(3E,5E,7E)-10-(tetrahydro-pyran-2-yloxy)-deca-3,5,7-trienyl]-phenoxy}-silane

Guidance literature:: Multi-step reaction with 3 steps

1.1: Bu₃SnH; AIBN / toluene / 4 h / Heating

1.2: 80 percent / I₂ / CH₂Cl₂ / 0.5 h

2.1: 45 percent / (CH₃CN)2PdCl₂ / dimethylformamide / 0.5 h / 25 °C

3.1: Bu₃SnCu(CN)Li / tetrahydrofuran / -40 °C

3.2: (CH₃CN)2PdCl₂ / dimethylformamide / 0.5 h / 20 °C

With 2,2'-azobis(isobutyronitrile); Bu₃SnCu(CN)Li; tri-n-butyl-tin hydride; dichloro bis(acetonitrile) palladium(II); In tetrahydrofuran; N,N-dimethyl-formamide; toluene; 1.1: Addition / 1.2: Oxidation / 2.1: Substitution / 3.1: Addition / 3.2: Substitution;
DOI:10.1016/S0040-4039(00)00532-3

Reference yield:

: 83918-48-3
(E)-tetrahydro-2-<(4-iodo-3-butenyl)oxy>-2H-pyran

: 287198-97-4
tert-Butyl-dimethyl-{4-[(3E,5E,7E)-10-(tetrahydro-pyran-2-yloxy)-deca-3,5,7-trienyl]-phenoxy}-silane

Guidance literature:: Multi-step reaction with 2 steps

1.1: 45 percent / (CH₃CN)2PdCl₂ / dimethylformamide / 0.5 h / 25 °C

2.1: Bu₃SnCu(CN)Li / tetrahydrofuran / -40 °C

2.2: (CH₃CN)2PdCl₂ / dimethylformamide / 0.5 h / 20 °C

With Bu₃SnCu(CN)Li; dichloro bis(acetonitrile) palladium(II); In tetrahydrofuran; N,N-dimethyl-formamide; 1.1: Substitution / 2.1: Addition / 2.2: Substitution;
DOI:10.1016/S0040-4039(00)00532-3