S-trans-Crotyl O-ethyl phenylphosphonothiolate

Base Information

• Chemical Name: S-trans-Crotyl O-ethyl phenylphosphonothiolate
• CAS No.: 85115-22-6
• Molecular Formula: C₁₂H₁₇O₂PS
• Molecular Weight: 256.306
• Mol file: 85115-22-6.mol

Synonyms:S-trans-Crotyl O-ethyl phenylphosphonothiolate

Chemical Property of S-trans-Crotyl O-ethyl phenylphosphonothiolate

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of S-trans-Crotyl O-ethyl phenylphosphonothiolate

There total 2 articles about S-trans-Crotyl O-ethyl phenylphosphonothiolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

O-trans-Crotyl O-ethyl phenylphosphonothionate (79428-88-9) → S-α-Methallyl O-ethyl phenylphosphonothiolate (79428-82-3) + S-trans-Crotyl O-ethyl phenylphosphonothiolate (85115-22-6)

Guidance literature:

With potassium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In diethylene glycol dimethyl ether; at 80 ℃; for 1h; Product distribution;

DOI:10.1021/jo00156a029

Reference yield:

Allyl ethyl phenylphosphonothionate (74070-90-9,97714-35-7,97714-36-8) + O-trans-Crotyl diethyl phosphorothionate (85083-08-5) → S-allyl-O,O-diethyl phosphorothioalate (10428-96-3) + S-trans-Crotyl diethyl phosphorothiolate (85083-00-7) + Phenyl-phosphonothioic acid S-allyl ester O-ethyl ester (74070-96-5) + S-trans-Crotyl O-ethyl phenylphosphonothiolate (85115-22-6)

Guidance literature:

With potassium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In diethylene glycol dimethyl ether; at 80 ℃; for 0.333333h; Product distribution;

DOI:10.1021/jo00156a029

upstream raw materials:

Allyl ethyl phenylphosphonothionate

O-trans-Crotyl diethyl phosphorothionate

O-trans-Crotyl O-ethyl phenylphosphonothionate