phenyl ferrocenoyl selenide

Base Information

• Chemical Name: phenyl ferrocenoyl selenide
• CAS No.: 779339-35-4
• Molecular Formula: C₁₇H₁₄FeOSe
• Molecular Weight: 369.105
• Mol file: 779339-35-4.mol

Synonyms:phenyl ferrocenoyl selenide

Chemical Property of phenyl ferrocenoyl selenide

Chemical Property:

Purity/Quality:

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Technology Process of phenyl ferrocenoyl selenide

There total 1 articles about phenyl ferrocenoyl selenide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

ferrocenoyl chloride (1293-79-4) + diphenyl diselenide (1666-13-3) → phenyl ferrocenoyl selenide (779339-35-4)

Guidance literature:

With LiBHEt₃; In tetrahydrofuran; (N2 or Ar); LiBHEt3 in THF added under Ar at 0°C to Se compd. in THF, stirred at this temp., Fe complex added at 0°C, stirred at 0°C and then at room temp.; extd. (Et2O), washed (satd. NaCl soln.), the org. layer dried (Na2SO4), evapd., flash-chromd. (silica gel, CH2Cl2/hexane), recrystd. (hexane/CH2Cl2); elem. anal.;

DOI:10.1016/j.jorganchem.2004.06.054

Reference yield:

phenyl ferrocenoyl selenide (779339-35-4) + thiophenol (108-98-5) → ferrocenecarboxaldehyde (12093-10-6)

Guidance literature:

In further solvent(s); in methanol and a phosphate buffer soln. for 1 h;

DOI:10.1016/j.jorganchem.2004.06.054

upstream raw materials:

ferrocenoyl chloride

diphenyl diselenide

Downstream raw materials:

ferrocenecarboxaldehyde