Chlorocarbonyl ferrocene

Base Information

• Chemical Name: Chlorocarbonyl ferrocene
• CAS No.: 1293-79-4
• Molecular Formula: C11H9ClFeO
• Molecular Weight: 248.492
• Mol file: 1293-79-4.mol

Synonyms:Chlorocarbonyl ferrocene

Chemical Property of Chlorocarbonyl ferrocene

Chemical Property:

• Boiling Point: 164.7 °C at 760 mmHg
• Flash Point: 69.7 °C
• PSA: 34.14000
• LogP: 2.31170
• Storage Temp.: ?20°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

Ferrocenoyl chloride for HPLC derivatization, ≥96.0% (AT) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C
• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Chlorocarbonyl ferrocene

There total 8 articles about Chlorocarbonyl ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

oxalyl dichloride (79-37-8) + ferrocenecarboxylic acid (1271-42-7) → ferrocenoyl chloride (1293-79-4)

Guidance literature:

In dichloromethane; refluxing of soln. of C5H5FeC5H4COOH and ClCOCOCl in CH2Cl2; removal of solvent and ClCOCOCl, drying in vac., washing with warm hexane;

DOI:10.1016/j.molstruc.2006.04.013

Reference yield: 94.0%

ferrocenecarboxylic acid (1271-42-7) + phosphorus trichloride (7719-12-2,52843-90-0) → ferrocenoyl chloride (1293-79-4)

Guidance literature:

In toluene; at 55 - 60 ℃; for 3h;

DOI:10.1016/j.jorganchem.2017.11.015

Reference yield: 85.0%

ferrocenecarboxylic acid (1271-42-7) → ferrocenoyl chloride (1293-79-4)

Guidance literature:

With pyridine; oxalyl dichloride; In dichloromethane; for 2h; Reflux;

DOI:10.1002/ejoc.201500647

upstream raw materials:

ferrocenecarboxylic acid

thionyl chloride

oxalyl dichloride

ferrocene

Downstream raw materials:

ferrocenecarboxaldehyde

triphenyltin chloride