[1-Anthracen-9-yl-meth-(E)-ylidene]-[3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-phenyl]-amine

Base Information

• Chemical Name: [1-Anthracen-9-yl-meth-(E)-ylidene]-[3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-phenyl]-amine
• CAS No.: 380151-96-2
• Molecular Formula: C₂₇H₂₆BNO₂
• Molecular Weight: 407.32
• Mol file: 380151-96-2.mol

Synonyms:[1-Anthracen-9-yl-meth-(E)-ylidene]-[3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-phenyl]-amine

Chemical Property of [1-Anthracen-9-yl-meth-(E)-ylidene]-[3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-phenyl]-amine

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of [1-Anthracen-9-yl-meth-(E)-ylidene]-[3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-phenyl]-amine

There total 1 articles about [1-Anthracen-9-yl-meth-(E)-ylidene]-[3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-phenyl]-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

9-anthracene aldehyde (642-31-9) + 3-aminophenylboronic acid pinacolate (210907-84-9) → [1-Anthracen-9-yl-meth-(E)-ylidene]-[3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-phenyl]-amine (380151-96-2)

Guidance literature:

With 4 A molecular sieve; In dichloromethane;

DOI:10.1139/v01-090

Reference yield: 69.0%

[1-Anthracen-9-yl-meth-(E)-ylidene]-[3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-phenyl]-amine (380151-96-2) + benzo[1,3,2]dioxaborole (274-07-7) → anthracen-9-ylmethyl-[3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-phenyl]-amine

Guidance literature:

With H₂O; In toluene; slight excess of catecholborane in toluene added dropwise to a stirred soln. of imine in toluene under N2; mixt. stored at room temp. for 24 h; water then added; extn.; flash chromy., Al2O3; elem. anal.;

DOI:10.1139/v01-090

Reference yield:

[1-Anthracen-9-yl-meth-(E)-ylidene]-[3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-phenyl]-amine (380151-96-2) → anthracen-9-ylmethyl-[3-(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)-phenyl]-amine

Guidance literature:

With sodium tetrahydroborate; In methanol;

DOI:10.1139/v01-090

upstream raw materials:

9-anthracene aldehyde

3-aminophenylboronic acid pinacolate