{(palladium)2manganese(Cl)(carbonyl)3(μ3-carbonyl)(μ-dppm)2}

Base Information

Chemical Name:{(palladium)2manganese(Cl)(carbonyl)3(μ3-carbonyl)(μ-dppm)2}
CAS No.:111026-27-8
Molecular Formula:C₅₉H₄₄Mn₂O₉P₄PdPt
Molecular Weight:1432.26
Hs Code.:

Synonyms:{(palladium)2manganese(Cl)(carbonyl)3(μ3-carbonyl)(μ-dppm)2}

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Chemical Property of {(palladium)2manganese(Cl)(carbonyl)3(μ3-carbonyl)(μ-dppm)2}

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Technology Process of {(palladium)2manganese(Cl)(carbonyl)3(μ3-carbonyl)(μ-dppm)2}

There total 3 articles about {(palladium)2manganese(Cl)(carbonyl)3(μ3-carbonyl)(μ-dppm)2} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 86028-11-7
{(palladium)2(manganese)2(carbonyl)8(μ3-carbonyl)(μ-dppm)2}

: 111026-27-8
{(palladium)2manganese(Cl)(carbonyl)3(μ3-carbonyl)(μ-dppm)2}

Guidance literature:: With aq. HCl; In dichloromethane; Addn. of 0.1 N HCl to Pd2Mn2(CO)9(μ-dppm) soln. in freshly distd. CH2Cl2, mixt. turns lowly from violet to green-brown.; Evapn. to dryness, washing of residue with H2O, extn. of solid with toluene gives green soln. and leaves insoluble brown material, filtering pptn. with n-hexane.;

Reference yield: 17.0%

: 13859-41-1
sodium-manganese pentacarbonyl

: 82307-36-6
{palladium-platinum(Cl)2(μ-dppm)}*CH2Cl2

: 10170-69-1
dimanganese decacarbonyl

: 111026-27-8
{(palladium)(platinum)(manganese)2(carbonyl)8(μ3-carbonyl)(μ-dppm)2}

Guidance literature:: In tetrahydrofuran; byproducts: NaCl; Addn. of a Na(Mn(CO)5) soln. to an orange suspn. of (PdPtCl2(μ-dppm)2) (cooling (-78°C), N2, stirring), color turns green-brown on raising temp. to ambient, stirring for 2 h.; Concg. in vac., pptg. with n-hexane, filtering of dark green-brown solid, washing with H2O, extg. with toluene gives orange-red soln. (contg. Mn2(CO)10), and a green solid.;

Reference yield:

: 86028-11-7
{(palladium)2(manganese)2(carbonyl)8(μ3-carbonyl)(μ-dppm)2}

: 56-34-8
tetraethylammonium chloride

: 60305-98-8
fac-{manganese(Cl)(carbonyl)3(dppm)}

: 111026-27-8
{(palladium)2manganese(Cl)(carbonyl)3(μ3-carbonyl)(μ-dppm)2}

Guidance literature:: In tetrahydrofuran; Under N2, addn. of (NEt4)Cl to suspn. of freshly prepd. Pd2-Mn2-complex, stirring (1,5 h), mixt. turns brown-green.; Evapn. in vac., filtn., washing of residue (H2O), drying, partly sol. in THF as brown-green soln., addn. of n-hexane gives mixt. of Pd2-Mn-complex and unidentified substance (IR), mother liquor gives fac-Mn-complex (IR, (1)H-NMR).;