[(η5-cyclopentadienyl)Fe(η5-C5H4CH2N(CH3)CH2C6H4NO2-4)]

Base Information

Chemical Name:[(η5-cyclopentadienyl)Fe(η5-C5H4CH2N(CH3)CH2C6H4NO2-4)]
CAS No.:910212-19-0
Molecular Formula:C₁₉H₂₀FeN₂O₂
Molecular Weight:364.227
Hs Code.:

Synonyms:[(η5-cyclopentadienyl)Fe(η5-C5H4CH2N(CH3)CH2C6H4NO2-4)]

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Chemical Property of [(η5-cyclopentadienyl)Fe(η5-C5H4CH2N(CH3)CH2C6H4NO2-4)]

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Technology Process of [(η5-cyclopentadienyl)Fe(η5-C5H4CH2N(CH3)CH2C6H4NO2-4)]

There total 1 articles about [(η5-cyclopentadienyl)Fe(η5-C5H4CH2N(CH3)CH2C6H4NO2-4)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 50-00-0,30525-89-4,61233-19-0
formaldehyd

: 910212-18-9
(η5-C5H5)Fe(η5-C5H4CH2NHCH2C6H4NO2-4)

: 910212-19-0
[(η5-cyclopentadienyl)Fe(η5-C5H4CH2N(CH3)CH2C6H4NO2-4)]

Guidance literature:: With sodium cyanoborohydride; acetic acid; In water; acetonitrile; sodium cyanoborohydride added to aq. formaldehyde and Fe-complex in MeCN, stirred for 30 min, CH3CO2H added dropwise, stirred at room temp. for 6 h; solvent removed, NaOH added, stirred for 30 min, extd. with Et2O, sepd.,organic layer dried over Na2SO4, column chromy. on silica gel with ethy l acetate/petroleum ether (1:5); elem. anal.;
DOI:10.1016/j.ica.2006.05.019

Reference yield: 78.0%

: sodium tetrachloropalladate(II)

: 910212-19-0
[(η5-cyclopentadienyl)Fe(η5-C5H4CH2N(CH3)CH2C6H4NO2-4)]

: 603-35-0
triphenylphosphine

: PdCl(PPh3)(η5-C5H5)Fe(η5-C5H3CH2N(CH3)CH2C6H4NO2-4)

Guidance literature:: With sodium acetate; In methanol; Na2PdCl4 in MeOH added dropwise to soln. of Fe-complex, NaCH3CO2 in MeOH, stirred for 4 h at room temp. under Ar, P(C6H5)3 added, stirred for 30min; solvent removed in vacuo, residue purified by column chromy. on silica gel with ethyl acetate/petroleum ether (1:1); elem. anal.;
DOI:10.1016/j.ica.2006.05.019

Reference yield: 40.0%

: 75992-73-3,25794-47-2,30729-25-0,15274-33-6,22840-91-1,14568-13-9
cis-dichlorobis(dimethylsulfoxide)platinum(II)

: 910212-19-0
[(η5-cyclopentadienyl)Fe(η5-C5H4CH2N(CH3)CH2C6H4NO2-4)]

: 913171-05-8
rac-σPt[(η5-Cp)Fe(η5-C5H3-CH2N(methyl)-benzyl-4'-nitro)](chloride)(DMSO)

Guidance literature:: In methanol; (N2); to a stirred soln. of amine in methanol cis-Pt(DMSO)2Cl2 added; mixture stirred and refluxed for 30 min; cooled back to room temp.; solvent removed in vacuo; water added; extracted with CH2Cl2 and separated; organic layer dried over anhydrous Na2SO4 and filtered; chromy. (silica gel, ethyl acetate/hexane=1:5 v/v); elem. anal.;
DOI:10.1016/j.poly.2006.02.017