(2R,3S)-2,3-bis<4-(tert-butyldimethylsiloxy)phenyl>pentyl carbethoxymethyl sulfide

Base Information

Chemical Name:(2R*,3S*)-2,3-bis<4-(tert-butyldimethylsiloxy)phenyl>pentyl carbethoxymethyl sulfide
CAS No.:107036-31-7
Molecular Formula:C₃₃H₅₄O₄SSi₂
Molecular Weight:603.026
Hs Code.:

Synonyms:(2R*,3S*)-2,3-bis<4-(tert-butyldimethylsiloxy)phenyl>pentyl carbethoxymethyl sulfide

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R*,3S*)-2,3-bis<4-(tert-butyldimethylsiloxy)phenyl>pentyl carbethoxymethyl sulfide

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Technology Process of (2R*,3S*)-2,3-bis<4-(tert-butyldimethylsiloxy)phenyl>pentyl carbethoxymethyl sulfide

There total 1 articles about (2R*,3S*)-2,3-bis<4-(tert-butyldimethylsiloxy)phenyl>pentyl carbethoxymethyl sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 105-36-2
ethyl bromoacetate

: 104946-98-7
(2R*,3S*)-2,3-bis<4-<(tert-butyldimethylsilyl)oxy>phenyl>-1-pentanethiol

: 107036-31-7
(2R*,3S*)-2,3-bis<4-(tert-butyldimethylsiloxy)phenyl>pentyl carbethoxymethyl sulfide

Guidance literature:: With potassium hydride; In tetrahydrofuran; at -78 - 25 ℃; for 1.25h;
DOI:10.1021/jm00388a015

Reference yield: 71.0%

: 107036-31-7
(2R*,3S*)-2,3-bis<4-(tert-butyldimethylsiloxy)phenyl>pentyl carbethoxymethyl sulfide

: 107036-32-8
(2R*,3S*)-2,3-bis<4-(tert-butyldimethylsiloxy)phenyl>pentyl 2-hydroxyethyl sulfide

Guidance literature:: With lithium aluminium tetrahydride; In tetrahydrofuran; at 25 ℃; for 0.333333h;
DOI:10.1021/jm00388a015

Reference yield:

: 107036-31-7
(2R*,3S*)-2,3-bis<4-(tert-butyldimethylsiloxy)phenyl>pentyl carbethoxymethyl sulfide

: 107036-14-6
(2R*,3S*)-2,3-bis(4-hydroxyphenyl)pentyl 2-N-aziridinylethyl sulfide

Guidance literature:: Multi-step reaction with 4 steps

1: 71 percent / LiAlH₄ / tetrahydrofuran / 0.33 h / 25 °C

2: Et₃N / tetrahydrofuran / 0.33 h / Ambient temperature

3: p-TsOH*H₂O / ethyl acetate / 0.33 h / 40 °C

4: 25 percent / Et₃N / acetonitrile / Ambient temperature

With lithium aluminium tetrahydride; toluene-4-sulfonic acid; triethylamine; In tetrahydrofuran; ethyl acetate; acetonitrile;
DOI:10.1021/jm00388a015