Pt(1,10-phenanthroline)(p-CCC₆H₄CHO)2

Base Information

• Chemical Name: Pt(1,10-phenanthroline)(p-CCC₆H₄CHO)2
• CAS No.: 560132-94-7
• Molecular Formula: C₃₀H₁₈N₂O₂Pt
• Molecular Weight: 633.565
• Mol file: 560132-94-7.mol

Synonyms:Pt(1,10-phenanthroline)(p-CCC₆H₄CHO)2

Chemical Property of Pt(1,10-phenanthroline)(p-CCC₆H₄CHO)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of Pt(1,10-phenanthroline)(p-CCC₆H₄CHO)2

There total 1 articles about Pt(1,10-phenanthroline)(p-CCC₆H₄CHO)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

dichloro(1,10-phenanthroline)platinum(II) (18432-95-6) + 4-Ethynylbenzaldehyde (63697-96-1) → Pt(1,10-phenanthroline)(p-CCC6H4CHO)2 (560132-94-7)

Guidance literature:

copper(l) iodide; In 1,2-dimethoxyethane; dimethyl sulfoxide; triethylamine; under N2; Pt-contg. compd. (0.22 mmol), CuI, 4-ethynylbenzaldehyde (2.5 mmol) and DMSO:DME:NEt3 (5:3:2 v/v/v) were placed into a Schlenk tube; the mixt. was stirred at 65°C for 20-24 h; the solvent was removed, H2O was added; vac. filtration; the solid was dissolved in CH2Cl2, repptd. by addn. of hexanes, and isolated by vac. filtration; preparative TLC on alumina (CH2Cl2/MeOH); recrystn. from CH2Cl2/hexanes; elem. anal.;

DOI:10.1021/ic0263084

Reference yield:

Pt(1,10-phenanthroline)(p-CCC6H4CHO)2 (560132-94-7) + L-homocysteine (6027-13-0) → Pt(N2C12H8)(CCC6H4C4H7SNCOOH)2

Guidance literature:

In water; acetonitrile; honocysteine (excess) added to soln. of Pt complex in MeCN-H2O (pH 7.2);reacted for 120 min; not isolated; monitored by UV-vis and photoluminescence spectra;

DOI:10.1016/j.ica.2008.11.026

Reference yield:

Pt(1,10-phenanthroline)(p-CCC6H4CHO)2 (560132-94-7) + L-Cysteine (52-90-4) → Pt(N2C12H8)(CCC6H4C3H5SNCOOH)2

Guidance literature:

In water; acetonitrile; cysteine (excess) added to soln. of Pt complex in MeCN-H2O (pH 7.2); reacted for 120 min; not isolated; monitored by UV-vis and photoluminescence spectra;

DOI:10.1016/j.ica.2008.11.026

upstream raw materials:

dichloro(1,10-phenanthroline)platinum(II)

4-Ethynylbenzaldehyde

Refernces

• 1、 Wadas, Thaddeus J.,Lachicotte, Rene J.,Eisenberg, Richard. "Synthesis and characterization of platinum diimine bis(acetylide) coplexes containing easily derivatizable aryl acetylide ligands". . p. 3772 - 3778. Retrieved 2008/10/08.