2-Methoxy-3-isopropyl-1,4-benzoquinone

Base Information

Chemical Name:2-Methoxy-3-isopropyl-1,4-benzoquinone
CAS No.:123151-46-2
Molecular Formula:C₁₀H₁₂O₃
Molecular Weight:180.203
Hs Code.:
DSSTox Substance ID:DTXSID701200044
Nikkaji Number:J2.223.292D

Synonyms:DTXSID701200044;2-Methoxy-3-isopropyl-1,4-benzoquinone;2-Methoxy-3-(1-methylethyl)-2,5-cyclohexadiene-1,4-dione;123151-46-2

Suppliers and Price of 2-Methoxy-3-isopropyl-1,4-benzoquinone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-Methoxy-3-isopropyl-1,4-benzoquinone

Chemical Property:

XLogP3:1.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:180.078644241
Heavy Atom Count:13
Complexity:308

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(C)C1=C(C(=O)C=CC1=O)OC

Technology Process of 2-Methoxy-3-isopropyl-1,4-benzoquinone

There total 4 articles about 2-Methoxy-3-isopropyl-1,4-benzoquinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

: 123151-45-1
3-methoxy-2-(1-methylethyl)phenol

: 123151-46-2
2-methoxy-3-isopropyl-1,4-benzoquinone

Guidance literature:: With salcomine; oxygen; In N,N-dimethyl-formamide; for 72h; Ambient temperature;
DOI:10.1021/jo00285a018

Reference yield:

: 16929-70-7
1,3-dimethoxy-2-(1-hydroxy-1-methylethyl)benzene

: 123151-46-2
2-methoxy-3-isopropyl-1,4-benzoquinone

Guidance literature:: Multi-step reaction with 3 steps

1: 85 percent / H₂, H₂SO₄ / 5percent Pd/C / ethyl acetate / 10 h / 2585.7 Torr / Ambient temperature

2: 89 percent / BBr₃ / CH₂Cl₂ / 1.) -78 deg C, 5 h, 2.) RT, 8 h

3: 44 percent / O₂, Co(salen) / dimethylformamide / 72 h / Ambient temperature

With salcomine; sulfuric acid; hydrogen; oxygen; boron tribromide; palladium on activated charcoal; In dichloromethane; ethyl acetate; N,N-dimethyl-formamide;
DOI:10.1021/jo00285a018

Reference yield:

: 151-10-0
1,3-Dimethoxybenzene

: 123151-46-2
2-methoxy-3-isopropyl-1,4-benzoquinone

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) t-BuLi/TMEDA / 1.) ether, hexane, -78 deg C, 5 h, 2.) 15 min

2: 85 percent / H₂, H₂SO₄ / 5percent Pd/C / ethyl acetate / 10 h / 2585.7 Torr / Ambient temperature

3: 89 percent / BBr₃ / CH₂Cl₂ / 1.) -78 deg C, 5 h, 2.) RT, 8 h

4: 44 percent / O₂, Co(salen) / dimethylformamide / 72 h / Ambient temperature

With salcomine; N,N,N,N,-tetramethylethylenediamine; sulfuric acid; hydrogen; tert.-butyl lithium; oxygen; boron tribromide; palladium on activated charcoal; In dichloromethane; ethyl acetate; N,N-dimethyl-formamide;
DOI:10.1021/jo00285a018