6’-O-tert-butyldiphenylsilyl-1’,2,3,3’,4,4’-hexa-O-benzylsucrose

Base Information

• Chemical Name: 6’-O-tert-butyldiphenylsilyl-1’,2,3,3’,4,4’-hexa-O-benzylsucrose
• CAS No.: 900525-72-6
• Molecular Formula: C₇₀H₇₆O₁₁Si
• Molecular Weight: 1121.45
• Mol file: 900525-72-6.mol

Synonyms:6’-O-tert-butyldiphenylsilyl-1’,2,3,3’,4,4’-hexa-O-benzylsucrose

Chemical Property of 6’-O-tert-butyldiphenylsilyl-1’,2,3,3’,4,4’-hexa-O-benzylsucrose

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 6’-O-tert-butyldiphenylsilyl-1’,2,3,3’,4,4’-hexa-O-benzylsucrose

There total 2 articles about 6’-O-tert-butyldiphenylsilyl-1’,2,3,3’,4,4’-hexa-O-benzylsucrose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

tert-butylchlorodiphenylsilane (58479-61-1) + 1’,2,3,3’,4,4’-hexa-O-benzylsucrose (74761-34-5) → 6’-O-tert-butyldiphenylsilyl-1’,2,3,3’,4,4’-hexa-O-benzylsucrose (900525-72-6) + 1’,2,3,3’,4,4’-hexa-O-benzyl-6,6’-di-O-tert-butyldiphenylsilylsucrose (1263312-76-0)

Guidance literature:

With dmap; N-ethyl-N,N-diisopropylamine; In dichloromethane; at 20 ℃; for 12h;

DOI:10.1080/07328303.2010.524958

Reference yield: 60.0%

tert-butylchlorodiphenylsilane (58479-61-1) + 1’,2,3,3’,4,4’-hexa-O-benzylsucrose (74761-34-5) → 6’-O-tert-butyldiphenylsilyl-1’,2,3,3’,4,4’-hexa-O-benzylsucrose (900525-72-6)

Guidance literature:

With dmap; N-ethyl-N,N-diisopropylamine; In dichloromethane; at 20 ℃;

DOI:10.1139/V06-035

Reference yield: 99.0%

6’-O-tert-butyldiphenylsilyl-1’,2,3,3’,4,4’-hexa-O-benzylsucrose (900525-72-6) + methanesulfonyl chloride (124-63-0) → 1',2,3,3',4,4'-hexa-O-benzyl-6'-O-(tert-butyldiphenylsilyl)-6-O-(methylsulfonyl)sucrose (1033507-59-3)

Guidance literature:

With dmap; triethylamine; In dichloromethane; at 20 ℃; for 4h;

DOI:10.1055/s-2008-1032198

upstream raw materials:

tert-butylchlorodiphenylsilane

1’,2,3,3’,4,4’-hexa-O-benzylsucrose

Downstream raw materials:

6-O-allyl-1',2,3,3',4,4'-hexa-O-benzyl-6'-O-tert-butyldiphenylsilylsucrose

6,6'-di-O-allyl-1',2,3,3',4,4'-hexa-O-benzylsucrose

6-O-allyl-1',2,3,3',4,4'-hexa-O-benzylsucrose

6-O-allyl-6'-O-acryloyl-1',2,3,3',4,4'-hexa-O-benzylsucrose