allyl 1-(3-(benzyloxy)propyl)-2-oxo-4-(phenylthio)cyclohex-3-enecarboxylate

Base Information

Chemical Name:allyl 1-(3-(benzyloxy)propyl)-2-oxo-4-(phenylthio)cyclohex-3-enecarboxylate
CAS No.:900493-88-1
Molecular Formula:C₂₆H₂₈O₄S
Molecular Weight:436.572
Hs Code.:

Synonyms:allyl 1-(3-(benzyloxy)propyl)-2-oxo-4-(phenylthio)cyclohex-3-enecarboxylate

Suppliers and Price of allyl 1-(3-(benzyloxy)propyl)-2-oxo-4-(phenylthio)cyclohex-3-enecarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of allyl 1-(3-(benzyloxy)propyl)-2-oxo-4-(phenylthio)cyclohex-3-enecarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of allyl 1-(3-(benzyloxy)propyl)-2-oxo-4-(phenylthio)cyclohex-3-enecarboxylate

There total 4 articles about allyl 1-(3-(benzyloxy)propyl)-2-oxo-4-(phenylthio)cyclohex-3-enecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

: 900493-69-8
allyl 2-oxo-4-(phenylthio)cyclohex-3-enecarboxylate

: 54314-84-0
1-[(3-bromopropoxy)methyl]-benzene

: 900493-88-1
allyl 1-(3-(benzyloxy)propyl)-2-oxo-4-(phenylthio)cyclohex-3-enecarboxylate

Guidance literature:: With tetra-(n-butyl)ammonium iodide; caesium carbonate; In N,N-dimethyl-formamide;
DOI:10.1002/anie.200504421

Reference yield:

: 75717-39-4
3-(phenylsulfanyl)cyclohex-2-en-1-one

: 900493-88-1
allyl 1-(3-(benzyloxy)propyl)-2-oxo-4-(phenylthio)cyclohex-3-enecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-Buli; diisopropylamine / toluene / 0.5 h / -78 °C

1.2: 75 percent / toluene / -78 - 23 °C

2.1: 39 percent / Cs₂CO₃; tetrabutylammonium iodide / dimethylformamide

With n-butyllithium; tetra-(n-butyl)ammonium iodide; caesium carbonate; diisopropylamine; In N,N-dimethyl-formamide; toluene;
DOI:10.1002/anie.200504421

Reference yield:

: 504-02-9
1,3-cylohexanedione

: 900493-88-1
allyl 1-(3-(benzyloxy)propyl)-2-oxo-4-(phenylthio)cyclohex-3-enecarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1.1: Et₃N; methanesulfonyl chloride / acetonitrile / 1 h / 0 - 25 °C

1.2: 85 percent / Et₃N / acetonitrile / 14 h / 0 - 25 °C

2.1: n-Buli; diisopropylamine / toluene / 0.5 h / -78 °C

2.2: 75 percent / toluene / -78 - 23 °C

3.1: 39 percent / Cs₂CO₃; tetrabutylammonium iodide / dimethylformamide

With n-butyllithium; tetra-(n-butyl)ammonium iodide; caesium carbonate; methanesulfonyl chloride; triethylamine; diisopropylamine; In N,N-dimethyl-formamide; toluene; acetonitrile;
DOI:10.1002/anie.200504421