54314-84-0

Basic information

• Product Name: BENZYL 3-BROMOPROPYL ETHER
• Synonyms: BENZYL 3-BROMOPROPYL ETHER;3-(BENZYLOXY)PROPYL BROMIDE;(3-BROMOPROPOXYMETHYL)BENZENE;1-[(3-BROMOPROPOXY)METHYL]BENZENE;Benzyl 3-bromopropyl;1-bromo-3-benzyloxypropane;Benzyl 3-bromopropyl ether,98%;Benzyl 3-bromoethyl ether
• CAS NO: 54314-84-0
• Molecular Formula: C₁₀H₁₃BrO
• Molecular Weight: 229.11
• EINECS: 1308068-626-2
• Product Categories: Phenyls & Phenyl-Het;Phenyls & Phenyl-Het;Ethers;Organic Building Blocks;Oxygen Compounds;alkyl bromide
• Mol File: 54314-84-0.mol
• Article Data: 22

Chemical Properties

• Boiling Point: 130-132 °C8 mm Hg(lit.)
• Flash Point: >230 °F
• Appearance: Colorless/Liquid
• Density: 1.298 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.032mmHg at 25°C
• Refractive Index: n20/D 1.531(lit.)
• Storage Temp.: Inert atmosphere,Room Temperature
• Water Solubility: Slightly soluble in water.
• CAS DataBase Reference: BENZYL 3-BROMOPROPYL ETHER(CAS DataBase Reference)
• NIST Chemistry Reference: BENZYL 3-BROMOPROPYL ETHER(54314-84-0)
• EPA Substance Registry System: BENZYL 3-BROMOPROPYL ETHER(54314-84-0)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39
• WGK Germany: 3
• Hazardous Substances Data: 54314-84-0(Hazardous Substances Data)

Usage

Chemical Properties

Clear colorless to yellow liquid

Uses

Benzyl 3-bromopropyl ether may be used in the studies of preparation of (2S,3S)-1-[(triisopropylsilyl)oxy]-7-(benzyloxy)-2,3-(isopropylidenedioxy)-4(Z)-heptene, Ppeparation of 5-(3-Benzyloxypropoxy)psoralen (PAP-7), total synthesis of zincophorin and (+)-anatoxin-a.

General Description

Benzyl 3-bromopropyl ether is an ether.

InChI:InChI=1/C10H13BrO/c11-7-4-8-12-9-10-5-2-1-3-6-10/h1-3,5-6H,4,7-9H2

Upstream product

• 868-84-8 S,S-dimethyl dithiocarbonate 
• 4799-68-2 3-benzyloxypropan-1-ol 
• 68-12-2 N,N-dimethyl-formamide 
• 100-39-0 benzyl bromide 
• 108-86-1 bromobenzene 
• 54314-83-9 1-bromo-3-(chloromethoxy)propane 
• 100-44-7 benzyl chloride 
• 70388-33-9 4-benzyloxybut-1-ene 
• 100-52-7 benzaldehyde 
• 772-01-0 2-phenyl-1,3-dioxane 
• 627-18-9 1-bromo-3-propanol 
• 100-51-6 benzyl alcohol 

Downstream Products

• 167755-39-7 ethyl 5-benzyloxypentanoate 
• 161892-68-8 2-(N-Benzylindol-2-yl)-2-(3-benzyloxypropyl)-1,3-dithian 
• 170750-04-6 1-4-dihydro-4-(3,4-dimethoxyphenyl)-2,6-dimethyl-1-(3-benzyloxypropyl)-3,5-dimethyl ester 
• 99701-67-4 2-Acetyl-5-benzyloxy-pentanoic acid ethyl ester 
• 201547-20-8 10-benzyloxy-3-(5-spiro-2,2-dimethyl-1,3-dioxacyclopentyl)-6-decyne-1-ol 
• 192197-15-2 Methyl 1-(3-benzyloxypropyl)-2-oxocyclopentanecarboxylate 
• 400835-53-2 (2R,3S,4S,5R,6R)-3-(3-Benzyloxy-propoxy)-2-(2,2-dimethoxy-ethoxy)-6-isobutoxymethyl-4,5-dimethoxy-tetrahydro-pyran 
• 400835-56-5 (2R,3S,4S,5R,6R)-3-(3-Benzyloxy-propoxy)-2-(3,3-diethoxy-propoxy)-6-isobutoxymethyl-4,5-dimethoxy-tetrahydro-pyran 
• 446264-06-8 7-benzyloxy-4-phenyl-hept-2-yn-1-ol 
• 752206-76-1 1-benzyloxy-7-methyl-7-octen-4-ol 
• 568591-86-6 ethyl 1-[3-(benzyloxy)propyl]cyclobutanecarboxylate 
• 937-61-1 benzyl propyl ether 
• 878553-01-6 3-(3-benzyloxy-propyl)-1H-indene 
• 192197-16-3 2-(3-Benzyloxypropyl)cyclopentan-1-one 

Relevant articles and documents

Synthesis of the Core Structure of Palhinine A

We present a strategy to the core structure of the alkaloid palhinine A passing through a 2,5-difunctionalized cyclohexenone. This enone was prepared by a domino Michael/aldol condensation sequence. An allylation reaction on the cyclohexenone followed by

Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow

A copper-based photocatalyst, Cu(tmp)(BINAP)BF4, was found to be active in a photoredox Appel-type conversion of alcohols to bromides. The catalyst was identified from a screening of 50 complexes and promoted the transformation of primary and secondary alcohols to their corresponding bromides and carboxylic acids to their anhydrides. The protocol was also amendable and optimized under continuous flow conditions.

Light-mediated deoxygenation of alcohols with a dimeric gold catalyst

A new protocol for the reductive deoxygenation of primary alcohols was explored. This photo-mediated method combines a novel approach to bromination of alcohols merged with the powerful reducing capability of [Au2(dppm)2]Cl2 [dppm = 1,1-bis(diphenylphosphino)methane] as a photoredox catalyst. The highly efficient methods discussed are marked by the use of UVA light-emitting diodes, which have significantly reduced reaction times and lowered setup cost.