Bis-(p-chlor-phenyl)-thiolphosphinsaeure-phenylester

Base Information

• Chemical Name: Bis-(p-chlor-phenyl)-thiolphosphinsaeure-phenylester
• CAS No.: 15929-45-0
• Molecular Formula: C₁₈H₁₃Cl₂OPS
• Molecular Weight: 379.246
• Mol file: 15929-45-0.mol

Synonyms:Bis-(p-chlor-phenyl)-thiolphosphinsaeure-phenylester

Chemical Property of Bis-(p-chlor-phenyl)-thiolphosphinsaeure-phenylester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Bis-(p-chlor-phenyl)-thiolphosphinsaeure-phenylester

There total 3 articles about Bis-(p-chlor-phenyl)-thiolphosphinsaeure-phenylester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

bis(4-chlorophenyl)phosphine oxide (15948-60-4) + thiophenol (108-98-5) → Bis-(p-chlor-phenyl)-thiolphosphinsaeure-phenylester (15929-45-0)

Guidance literature:

With tert-Butyl peroxybenzoate; potassium iodide; In dimethyl sulfoxide; at 20 ℃; for 8h;

DOI:10.1039/c4gc00944d

Reference yield:

bis(4-chlorophenyl)phosphine oxide (15948-60-4) + diphenyldisulfane (882-33-7) → Bis-(p-chlor-phenyl)-thiolphosphinsaeure-phenylester (15929-45-0)

Guidance literature:

With hydroquinone; In tert-butyl alcohol;

DOI:10.1016/0040-4020(67)85057-9

Reference yield:

bromochlorobenzene (106-39-8) → Bis-(p-chlor-phenyl)-thiolphosphinsaeure-phenylester (15929-45-0)

Guidance literature:

Multi-step reaction with 2 steps

1.1: iodine; magnesium / tetrahydrofuran / 20 °C

1.2: -15 - 20 °C

2.1: tert-Butyl peroxybenzoate; potassium iodide / dimethyl sulfoxide / 8 h / 20 °C

With tert-Butyl peroxybenzoate; iodine; magnesium; potassium iodide; In tetrahydrofuran; dimethyl sulfoxide;

DOI:10.1039/c4gc00944d

upstream raw materials:

bis(4-chlorophenyl)phosphine oxide

diphenyldisulfane

thiophenol

bromochlorobenzene