CID 6100622

Base Information

Chemical Name:CID 6100622
CAS No.:15096-68-1
Molecular Formula:C₇H₃NO₅W
Molecular Weight:364.955
Hs Code.:

Synonyms:

Suppliers and Price of CID 6100622

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
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Total 0 raw suppliers

Chemical Property of CID 6100622

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:0
Exact Mass:364.952055
Heavy Atom Count:14
Complexity:39.3

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC#N.[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[W]

Technology Process of CID 6100622

There total 8 articles about CID 6100622 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: pentacarbonyl(diphenylcarben)wolfram

: 75-05-8,26809-02-9
acetonitrile

: 16800-45-6,29890-10-6,53447-66-8
cis-W(CO)4(acetonitrile)2

: 15096-68-1
pentacarbonyl(acetonitrile)tungsten

: pentacarbonyl{diphenylmethyleneamino(methyl)carbene}tungsten

Guidance literature:: In acetonitrile; byproducts: diphenylketene; stirring at 50°C for 30 min (N2); evapn., chromy. (Kieselgel, -20°C) yields first (pentane/CH2Cl2) dinitrile complex (evapn., recrystn. (pentane/CH2Cl2)), then (CH2Cl2) nitrile complex (evapn., -20°C, high vac., elem. anal.); carbene complex and Ph2CCO are detected by IR;
DOI:10.1016/0022-328X(87)80228-0

Reference yield: 61.0%

: 125475-73-2
bis(acetonitrile)bromo(pentafluorophenyl)palladium(II)

: [(C₆H₅CHCHCN(C₂H₅)2)W(CO)5]

: 15096-68-1
pentacarbonyl(acetonitrile)tungsten

: trans-[Pd(.mu-Br)(C₆F₅)(PhCH=CHC(NEt₂))]2

Guidance literature:: In dichloromethane; Schlenk technique; Pd complex was added to soln. of W complex in CH2Cl2;mixt. was stirred for 30 min; filtered through activated C and Celite; evapd.; Et2O added; kept at -20°C for 12 h; filtered; washed (pentane); dried (vac.);
DOI:10.1021/om051028s

Reference yield: 42.0%

: 125475-73-2
bis(acetonitrile)bromo(pentafluorophenyl)palladium(II)

: [W(CO)5(C(OCH₃)CHCHCH₃)]

: 15096-68-1
pentacarbonyl(acetonitrile)tungsten

: 1219103-64-6
(OCH₃)C(C₆F₅)CHCH(C₆F₅)CH₃

: 1219103-65-7,1219453-83-4
[Pd(μ-Br)(η3-C(C6F5)(OMe)CHCHMe)]2

Guidance literature:: In CH₂Cl₂; under inert gas; to soln. of W(CO)5C(OMe)CHCHMe (0.613 mmol) in CH2Cl2 Pd(C6F5)Br(NCMe)2 (0.613 mmol) added, stirred for 4 h at room temp.; filtered (activated carbon), solvent removed, triturated (pentane), filtered, washed (pentane), vacuum-dried; elem. anal.;
DOI:10.1016/j.jorganchem.2009.10.027