Copper, [1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-hexadecachloro-29H,31H-phthalocyaninato(2-)-kappaN29,kappaN30,kappaN31,kappaN32]-, (SP-4-1)-

Base Information

• Chemical Name: Copper, [1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-hexadecachloro-29H,31H-phthalocyaninato(2-)-kappaN29,kappaN30,kappaN31,kappaN32]-, (SP-4-1)-
• CAS No.: 14832-14-5
• Molecular Formula: C32Cl16CuN8
• Molecular Weight: 1127.2
• Hs Code.: 3204170000
• Wikipedia: Phthalocyanine_Green_G
• Wikidata: Q413867
• Mol file: 14832-14-5.mol

Synonyms:Copper, [1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-hexadecachloro-29H,31H-phthalocyaninato(2-)-.kappa.N29,.kappa.N30,.kappa.N31,.kappa.N32]-, (SP-4-1)-;Phthalocyanine Green G;Q413867

Chemical Property of Copper, [1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-hexadecachloro-29H,31H-phthalocyaninato(2-)-kappaN29,kappaN30,kappaN31,kappaN32]-, (SP-4-1)-

Chemical Property:

• PSA: 90.94000
• LogP: 11.91630
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 0
• Exact Mass: 1126.444032
• Heavy Atom Count: 57
• Complexity: 1170

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C12=C(C(=C(C(=C1Cl)Cl)Cl)Cl)C3=NC4=NC(=NC5=NC(=NC6=C7C(=C([N-]6)N=C2[N-]3)C(=C(C(=C7Cl)Cl)Cl)Cl)C8=C5C(=C(C(=C8Cl)Cl)Cl)Cl)C9=C4C(=C(C(=C9Cl)Cl)Cl)Cl.[Cu+2]

Technology Process of Copper, [1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-hexadecachloro-29H,31H-phthalocyaninato(2-)-kappaN29,kappaN30,kappaN31,kappaN32]-, (SP-4-1)-

There total 6 articles about Copper, [1,2,3,4,8,9,10,11,15,16,17,18,22,23,24,25-hexadecachloro-29H,31H-phthalocyaninato(2-)-kappaN29,kappaN30,kappaN31,kappaN32]-, (SP-4-1)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

C32H8Cl8CuN8, β (28107-34-8) → C32Cl16CuN8, β (14832-14-5)

Guidance literature:

In neat (no solvent); chlorination of (CuC32H8Cl8N8) in presence of freshly recrystd. Sb2S3 at 200-210°C;;

Reference yield:

tetrachlorophthalic anhydride (117-08-8) + urea (57-13-6) + copper(l) chloride → C32Cl16CuN8, β (14832-14-5)

Guidance literature:

ammonium molybdate; In further solvent(s); tetrachloro-phthalic acid anhydride, urea and CuCl in the diluent polychlorobenzene or trichlorobenzene in the presence of (NH4)2MoO4 as catalyst; various temp.;; impurities: chlorphthalocyanine;;

Reference yield:

tetrachlorophthalic anhydride (117-08-8) + copper (12775-96-1,15158-11-9,15721-63-8,16941-75-6,17493-86-6,19498-52-3,20499-83-6,20499-84-7,20499-85-8,20499-86-9,20573-10-8,20573-11-9,21595-51-7,21595-52-8,22206-52-6,26445-28-3,28959-95-7,37362-93-9,39417-05-5,54603-16-6,54603-23-5,54603-32-6,54603-40-6,54603-48-4,54603-81-5,54603-89-3,56316-56-4,95985-91-4,122297-32-9,7440-50-8) + urea (57-13-6) → C32Cl16CuN8, β (14832-14-5)

Guidance literature:

arsenic(V) oxide; In nitrobenzene; tetrachloro-phthalic acid anhydride, urea and Cu in the diluent nitrobenzene in the presence of As2O5 as catalyst;; impurities: chlorphthalocyanine;;

upstream raw materials:

tetrachlorophthalonitrile

copper diacetate

tetrachlorophthalic anhydride

urea

Refernces

• 1、 Raja, Robert,Ratnasamy, Paul. "Oxyhalogenation of Aromatics over Copper Phthalocyanines Encapsulated in Zeolites". . p. 244 - 253. Retrieved 2007/10/03.