CpRe(PPh₃)(NO)(CH₂OMe)

Base Information

Chemical Name:CpRe(PPh₃)(NO)(CH₂OMe)
CAS No.:71763-31-0
Molecular Formula:C₂₅H₂₅NO₂PRe
Molecular Weight:588.66
Hs Code.:

CpRe(PPh<SUB>3</SUB>)(NO)(CH<SUB>2</SUB>OMe)

Synonyms:CpRe(PPh₃)(NO)(CH₂OMe)

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Chemical Property of CpRe(PPh₃)(NO)(CH₂OMe)

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Technology Process of CpRe(PPh₃)(NO)(CH₂OMe)

There total 3 articles about CpRe(PPh₃)(NO)(CH₂OMe) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: (η5-C5H5)(Me)(NO)(PPh3)rhenium(II)

: 437-17-2
tritylium hexafluorophosphate

: 71763-31-0
CpRe(PPh₃)(NO)(CH₂OMe)

Guidance literature:: With methanol; sodium; In dichloromethane; -78°C, 0.5 h, addn. of Ph3CPF6, slowly warm to room temp. under N2; solvent vac. distd., residue extd. with benzene, extract filtered and concd., and hexane layered on benzene, crystals isolated by filtration, vac. drying;
DOI:10.1021/ja00365a027

Reference yield: 93.0%

: {(η5-C5H5)Re(NO)(PPh3)(CHO)}

: 71763-33-2
(C₅H₅)ReNO(CHOCH₃)P(C₆H₅)3⁽¹⁺⁾*SO₃F^(1-)*(0.33-0.40)C₆H₅CH₃

: 71763-31-0
CpRe(PPh₃)(NO)(CH₂OMe)

: 71763-17-2
(C₅H₅)ReNOCO{P(C₆H₅)3}⁽¹⁺⁾*SO₃F^(1-)=(C₅H₅)ReNOCOP(C₆H₅)3SO₃F

Guidance literature:: In chloroform-d1; -23°C, warmed to room temp. under N2; detected by NMR, the solid was filtered and washed with hexane;
DOI:10.1021/ja00365a027

Reference yield: 57.0%

: 71763-30-9
(C₅H₅)ReNO{P(C₆H₅)3}(CH₂NC₅H₅)⁽¹⁺⁾*PF₆^(1-)=(C₅H₅)ReNOP(C₆H₅)3CH₂NC₅H₅PF₆

: 124-41-4
sodium methylate

: 71763-31-0
CpRe(PPh₃)(NO)(CH₂OMe)

Guidance literature:: In methanol; stirring at ambient temp. 1 h under N2; solvent vac. distd., residue extd. with benzene, filtered and the solvent was removed from the filtrate by vac. distn., recrystd., elem. anal.;
DOI:10.1021/ja00365a027