(S)-(-)-5-tert-butyldimethylsilanyloxy-1-methyl-2-(triethylsilanyloxy)cyclohexa-1,3-diene

Base Information

Chemical Name:(S)-(-)-5-tert-butyldimethylsilanyloxy-1-methyl-2-(triethylsilanyloxy)cyclohexa-1,3-diene
CAS No.:1020850-47-8
Molecular Formula:C₁₉H₃₈O₂Si₂
Molecular Weight:354.681
Hs Code.:

Synonyms:(S)-(-)-5-tert-butyldimethylsilanyloxy-1-methyl-2-(triethylsilanyloxy)cyclohexa-1,3-diene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-(-)-5-tert-butyldimethylsilanyloxy-1-methyl-2-(triethylsilanyloxy)cyclohexa-1,3-diene

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Technology Process of (S)-(-)-5-tert-butyldimethylsilanyloxy-1-methyl-2-(triethylsilanyloxy)cyclohexa-1,3-diene

There total 1 articles about (S)-(-)-5-tert-butyldimethylsilanyloxy-1-methyl-2-(triethylsilanyloxy)cyclohexa-1,3-diene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 994-30-9
triethylsilyl chloride

: 1020850-34-3
(4S₆R,4S₆S)-4-tert-butyldimethylsilyloxy-6-methylcyclohex-2-en-1-one

: 1020850-47-8
(S)-(-)-5-tert-butyldimethylsilanyloxy-1-methyl-2-(triethylsilanyloxy)cyclohexa-1,3-diene

Guidance literature:: (4S₆R,4S₆S)-4-tert-butyldimethylsilyloxy-6-methylcyclohex-2-en-1-one; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 1h;

triethylsilyl chloride; In tetrahydrofuran; at -78 - 20 ℃; for 1h; Further stages.;
DOI:10.1002/anie.200705329

Reference yield: 83.0%

: 1020850-47-8
(S)-(-)-5-tert-butyldimethylsilanyloxy-1-methyl-2-(triethylsilanyloxy)cyclohexa-1,3-diene

: 1020850-48-9
(4S,6S)-(-)-4-(tert-butyldimethylsilanyloxy)-6-hydroxy-6-methyl-cyclohex-2-en-1-one

: 1020850-49-0
(4S,6R)-(-)-4-(tert-butyldimethylsilanyloxy)-6-hydroxy-6-methyl-cyclohex-2-en-1-one

Guidance literature:: With 3,3-dimethyldioxirane; In dichloromethane; acetone; at -50 ℃; for 0.833333h; diastereoselective reaction;
DOI:10.1002/ejoc.200800558