dithiocarbonic acid O-[3-(2,6-dimethoxy-3-methyl-phenyl)-2,2,3-trimethyl-cyclopentyl] ester S-methyl ester

Base Information

Chemical Name:dithiocarbonic acid O-[3-(2,6-dimethoxy-3-methyl-phenyl)-2,2,3-trimethyl-cyclopentyl] ester S-methyl ester
CAS No.:913300-16-0
Molecular Formula:C₁₉H₂₈O₃S₂
Molecular Weight:368.562
Hs Code.:

dithiocarbonic acid <i>O</i>-[3-(2,6-dimethoxy-3-methyl-phenyl)-2,2,3-trimethyl-cyclopentyl] ester <i>S</i>-methyl ester

Synonyms:dithiocarbonic acid O-[3-(2,6-dimethoxy-3-methyl-phenyl)-2,2,3-trimethyl-cyclopentyl] ester S-methyl ester

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Chemical Property of dithiocarbonic acid O-[3-(2,6-dimethoxy-3-methyl-phenyl)-2,2,3-trimethyl-cyclopentyl] ester S-methyl ester

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Technology Process of dithiocarbonic acid O-[3-(2,6-dimethoxy-3-methyl-phenyl)-2,2,3-trimethyl-cyclopentyl] ester S-methyl ester

There total 3 articles about dithiocarbonic acid O-[3-(2,6-dimethoxy-3-methyl-phenyl)-2,2,3-trimethyl-cyclopentyl] ester S-methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 913300-15-9
4-(2,6-dimethoxy-3-methylphenyl)-4,5,5-trimethylcyclopentanol

: 75-15-0,12122-00-8
carbon disulfide

: 74-88-4
methyl iodide

: 913300-16-0
dithiocarbonic acid O-[3-(2,6-dimethoxy-3-methyl-phenyl)-2,2,3-trimethyl-cyclopentyl] ester S-methyl ester

Guidance literature:: 4-(2,6-dimethoxy-3-methylphenyl)-4,5,5-trimethylcyclopentanol; carbon disulfide; With 1H-imidazole; sodium hydride; In tetrahydrofuran; for 0.25h; Heating;

methyl iodide; In tetrahydrofuran; for 4h; Heating;
DOI:10.1016/j.tet.2006.07.062

Reference yield:

: 913300-13-7
4-(2,6-dimethoxy-3-methylphenyl)-4,5,5-trimethylcyclopent-2-enone

: 913300-16-0
dithiocarbonic acid O-[3-(2,6-dimethoxy-3-methyl-phenyl)-2,2,3-trimethyl-cyclopentyl] ester S-methyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: 100 percent / hydrogen / Pd/C / ethanol / 1 h / 20 °C

2.1: 99 percent / sodium borohydride / methanol / 0.08 h / cooling

3.1: sodium hydride; imidazole / tetrahydrofuran / 0.25 h / Heating

3.2: 88 percent / tetrahydrofuran / 4 h / Heating

With 1H-imidazole; sodium tetrahydroborate; hydrogen; sodium hydride; palladium on activated charcoal; In tetrahydrofuran; methanol; ethanol;
DOI:10.1016/j.tet.2006.07.062

Reference yield:

: 913300-14-8
4-(2,6-dimethoxy-3-methylphenyl)-4,5,5-trimethylcyclopentanone

: 913300-16-0
dithiocarbonic acid O-[3-(2,6-dimethoxy-3-methyl-phenyl)-2,2,3-trimethyl-cyclopentyl] ester S-methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: 99 percent / sodium borohydride / methanol / 0.08 h / cooling

2.1: sodium hydride; imidazole / tetrahydrofuran / 0.25 h / Heating

2.2: 88 percent / tetrahydrofuran / 4 h / Heating

With 1H-imidazole; sodium tetrahydroborate; sodium hydride; In tetrahydrofuran; methanol;
DOI:10.1016/j.tet.2006.07.062