1,4-dimethyl-4-<3-<(methylsulfonyl)oxy>-1-methyl-2-oxocyclopentyl>-2-cyclohexen-1-ol

Base Information

Chemical Name:1,4-dimethyl-4-<3-<(methylsulfonyl)oxy>-1-methyl-2-oxocyclopentyl>-2-cyclohexen-1-ol
CAS No.:122444-68-2
Molecular Formula:C₁₅H₂₄O₅S
Molecular Weight:316.419
Hs Code.:

Synonyms:1,4-dimethyl-4-<3-<(methylsulfonyl)oxy>-1-methyl-2-oxocyclopentyl>-2-cyclohexen-1-ol

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Chemical Property of 1,4-dimethyl-4-<3-<(methylsulfonyl)oxy>-1-methyl-2-oxocyclopentyl>-2-cyclohexen-1-ol

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Technology Process of 1,4-dimethyl-4-<3-<(methylsulfonyl)oxy>-1-methyl-2-oxocyclopentyl>-2-cyclohexen-1-ol

There total 1 articles about 1,4-dimethyl-4-<3-<(methylsulfonyl)oxy>-1-methyl-2-oxocyclopentyl>-2-cyclohexen-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 75-16-1
methylmagnesium bromide

: 122444-66-0
1-methyl-1-<3-<(methylsulfonyl)oxy>-1-methyl-2-oxocyclopentyl>cyclohex-2-en-4-one

: 122444-68-2
1,4-dimethyl-4-<3-<(methylsulfonyl)oxy>-1-methyl-2-oxocyclopentyl>-2-cyclohexen-1-ol

Guidance literature:: In tetrahydrofuran; diethyl ether; at -78 ℃; for 4h;
DOI:10.1021/jo00280a039

Reference yield: 87.0%

: 122444-68-2
1,4-dimethyl-4-<3-<(methylsulfonyl)oxy>-1-methyl-2-oxocyclopentyl>-2-cyclohexen-1-ol

: 122444-69-3
3,6-dimethyl-6-<3-<(methylsulfonyl)oxy>-1-methyl-2-oxocyclopentyl>-2-cyclohexen-1-one

Guidance literature:: With pyridinium chlorochromate; In dichloromethane; for 3h; Ambient temperature;
DOI:10.1021/jo00280a039

Reference yield:

: 122444-68-2
1,4-dimethyl-4-<3-<(methylsulfonyl)oxy>-1-methyl-2-oxocyclopentyl>-2-cyclohexen-1-ol

: 54713-64-3,60769-55-3,114883-14-6
trichotheca-9,12-diene

Guidance literature:: Multi-step reaction with 4 steps

1: 87 percent / pyridinium chlorochromate / CH₂Cl₂ / 3 h / Ambient temperature

2: 92 percent / 1.0 M diisobutylaluminum hydride (DiBAH) / CH₂Cl₂; hexane / 0.5 h / Ambient temperature

3: 91 percent / pyridinium chlorochromate / CH₂Cl₂ / 3 h / Ambient temperature

4: 1.) ^tBuOK / 1.) Et₂O, ^tBuOH, reflux, 1 h, 2.) ether, reflux, 4 h

With potassium tert-butylate; diisobutylaluminium hydride; pyridinium chlorochromate; In hexane; dichloromethane;
DOI:10.1021/jo00280a039