(1S,2R,5S)-(-)-(E)-cinnamyl cis-myrtanyl selenide

Base Information

• Chemical Name: (1S,2R,5S)-(-)-(E)-cinnamyl cis-myrtanyl selenide
• CAS No.: 1462351-89-8
• Molecular Formula: C₁₉H₂₆Se
• Molecular Weight: 333.375
• Mol file: 1462351-89-8.mol

Synonyms:(1S,2R,5S)-(-)-(E)-cinnamyl cis-myrtanyl selenide

Chemical Property of (1S,2R,5S)-(-)-(E)-cinnamyl cis-myrtanyl selenide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1S,2R,5S)-(-)-(E)-cinnamyl cis-myrtanyl selenide

There total 1 articles about (1S,2R,5S)-(-)-(E)-cinnamyl cis-myrtanyl selenide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

trans-3-phenylprop-2-enyl chloride (21087-29-6) + (1S,2R,5S)-(-)-cis-myrtanyl selenol (1462351-61-6) → (1S,2R,5S)-(-)-(E)-cinnamyl cis-myrtanyl selenide (1462351-89-8)

Guidance literature:

(1S,2R,5S)-(-)-cis-myrtanyl selenol; With n-butyllithium; In tetrahydrofuran; at -25 ℃; for 0.5h; Inert atmosphere;

trans-3-phenylprop-2-enyl chloride; In tetrahydrofuran; at 0 - 50 ℃; for 1h;

DOI:10.1016/j.tetasy.2013.07.018

Reference yield:

(1S,2R,5S)-(-)-(E)-cinnamyl cis-myrtanyl selenide (1462351-89-8) → (1S,2R,5S)-(-)-(E)-cinnamyl cis-myrtanyl selenoxide

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -78 - -25 ℃; Inert atmosphere;

DOI:10.1016/j.tetasy.2013.07.018

Reference yield:

(1S,2R,5S)-(-)-(E)-cinnamyl cis-myrtanyl selenide (1462351-89-8) → (R)-1-phenylprop-2-en-1-ol (104713-12-4) + (1S)-1-phenylprop-2-en-1-ol (104713-12-4)

Guidance literature:

Multi-step reaction with 2 steps

1.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / -78 - -25 °C / Inert atmosphere

2.1: triethylamine / dichloromethane / -25 - 25 °C

2.2: 25 °C

With triethylamine; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;

DOI:10.1016/j.tetasy.2013.07.018

upstream raw materials:

trans-3-phenylprop-2-enyl chloride

(1S,2R,5S)-(-)-cis-myrtanyl selenol

Downstream raw materials:

(R)-1-phenylprop-2-en-1-ol

(1S)-1-phenylprop-2-en-1-ol