(S,Z)-3-[1-(1-benzyl-1H-pyrrol-2-yl)-4-methyl-1-oxopent-2-en-2-yl]-4-phenyloxazolidin-2-one

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Chemical Name:(S,Z)-3-[1-(1-benzyl-1H-pyrrol-2-yl)-4-methyl-1-oxopent-2-en-2-yl]-4-phenyloxazolidin-2-one
CAS No.:1370641-36-3
Molecular Formula:C₂₆H₂₆N₂O₃
Molecular Weight:414.504
Hs Code.:

Synonyms:(S,Z)-3-[1-(1-benzyl-1H-pyrrol-2-yl)-4-methyl-1-oxopent-2-en-2-yl]-4-phenyloxazolidin-2-one

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Chemical Property of (S,Z)-3-[1-(1-benzyl-1H-pyrrol-2-yl)-4-methyl-1-oxopent-2-en-2-yl]-4-phenyloxazolidin-2-one

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Technology Process of (S,Z)-3-[1-(1-benzyl-1H-pyrrol-2-yl)-4-methyl-1-oxopent-2-en-2-yl]-4-phenyloxazolidin-2-one

There total 1 articles about (S,Z)-3-[1-(1-benzyl-1H-pyrrol-2-yl)-4-methyl-1-oxopent-2-en-2-yl]-4-phenyloxazolidin-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 1370641-43-2
(4S)-3-(3-methylbut-1-yn-1-yl)-4-phenyl-1,3-oxazolidin-2-one

: 51491-77-1
1-benzyl-1H-pyrrole-2-carbonyl chloride

: 1370641-36-3
(S,Z)-3-[1-(1-benzyl-1H-pyrrol-2-yl)-4-methyl-1-oxopent-2-en-2-yl]-4-phenyloxazolidin-2-one

Guidance literature:: (4S)-3-(3-methylbut-1-yn-1-yl)-4-phenyl-1,3-oxazolidin-2-one; With tetrakis(triphenylphosphine) palladium⁽⁰⁾; tri-n-butyl-tin hydride; In dichloromethane; at 0 - 20 ℃; for 0.533333h; Inert atmosphere;

1-benzyl-1H-pyrrole-2-carbonyl chloride; With copper(I) thiophene-2-carboxylate; In dichloromethane; regioselective reaction; Inert atmosphere;
DOI:10.1021/ol300316a

Reference yield: 94.0%

: 1370641-36-3
(S,Z)-3-[1-(1-benzyl-1H-pyrrol-2-yl)-4-methyl-1-oxopent-2-en-2-yl]-4-phenyloxazolidin-2-one

: 1370641-15-8
(S)-3-{(4S,5R)-1-benzyl-4-isopropyl-6-oxo-1,4,5,6-tetrahydrocyclopenta[b]pyrrol-5-yl}-4-phenyloxazolidin-2-one

Guidance literature:: With methanesulfonic acid; In dichloromethane; at 0 ℃; optical yield given as %de; stereoselective reaction; Inert atmosphere; Reflux;
DOI:10.1021/ol300316a