Methyl 4-azido-4,6-dideoxy-3-O-benzyl-2-O-p-methoxybenzyl-α-D-mannopyranoside

Base Information

Chemical Name:Methyl 4-azido-4,6-dideoxy-3-O-benzyl-2-O-p-methoxybenzyl-α-D-mannopyranoside
CAS No.:163072-25-1
Molecular Formula:C₂₂H₂₇N₃O₅
Molecular Weight:413.473
Hs Code.:

Synonyms:Methyl 4-azido-4,6-dideoxy-3-O-benzyl-2-O-p-methoxybenzyl-α-D-mannopyranoside

Suppliers and Price of Methyl 4-azido-4,6-dideoxy-3-O-benzyl-2-O-p-methoxybenzyl-α-D-mannopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of Methyl 4-azido-4,6-dideoxy-3-O-benzyl-2-O-p-methoxybenzyl-α-D-mannopyranoside

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of Methyl 4-azido-4,6-dideoxy-3-O-benzyl-2-O-p-methoxybenzyl-α-D-mannopyranoside

There total 1 articles about Methyl 4-azido-4,6-dideoxy-3-O-benzyl-2-O-p-methoxybenzyl-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.5%

: 115196-83-3
methyl 4-azido-3-O-benzyl-4,6-dideoxy-α-D-mannopyranoside

: 824-94-2
p-methoxybenzyl chloride

: 163072-25-1
Methyl 4-azido-4,6-dideoxy-3-O-benzyl-2-O-p-methoxybenzyl-α-D-mannopyranoside

Guidance literature:: With potassium hydroxide; In dimethyl sulfoxide; for 1h; Ambient temperature;

Reference yield: 91.5%

: 163072-25-1
Methyl 4-azido-4,6-dideoxy-3-O-benzyl-2-O-p-methoxybenzyl-α-D-mannopyranoside

: 163072-26-2
Methyl 4-amino-4,6-dideoxy-3-O-benzyl-2-O-p-methoxybenzyl-α-D-mannopyranoside

Guidance literature:: With pyridine; hydrogen sulfide; triethylamine; Ambient temperature;

Reference yield:

: 163072-25-1
Methyl 4-azido-4,6-dideoxy-3-O-benzyl-2-O-p-methoxybenzyl-α-D-mannopyranoside

: 163072-32-0
Methyl 2-O-<2,3-di-O-benzoyl-4,6-dideoxy-4-(2,4-di-O-benzoyl-3-deoxy-L-glycero-tetronamido)-α-D-mannopyranosyl>-4,6-dideoxy-4-(2,4-di-O-benzoyl-3-deoxy-L-glycero-tetronamido)-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 91.5 percent / H₂S, pyridine, Et₃N / Ambient temperature

2: 1.) pyridine, 2.) NaOMe / 1.) 105-110 deg C, 16 h, 2.) MeOH, r.t., overnight

3: 77 percent / pyridine / Ambient temperature

4: 91 percent / CAN / acetonitrile; H₂O / 0.5 h / Ambient temperature

5: 81 percent / 2,4,6-trimethylpyridine, AgOTf / CH₂Cl₂ / 1 h / 0 °C

6: 100 percent / H₂ / 5percent Pd/C / acetone; ethanol

With pyridine; 2,4,6-trimethyl-pyridine; ammonium cerium(IV) nitrate; hydrogen sulfide; hydrogen; sodium methylate; silver trifluoromethanesulfonate; triethylamine; palladium on activated charcoal; In ethanol; dichloromethane; water; acetone; acetonitrile;