2-benzenesulfinyl-1-methyl-3-(4-trimethylsilylmethyl-pent-4-enyl)-1H-indole

Base Information

Chemical Name:2-benzenesulfinyl-1-methyl-3-(4-trimethylsilylmethyl-pent-4-enyl)-1H-indole
CAS No.:712273-30-8
Molecular Formula:C₂₄H₃₁NOSSi
Molecular Weight:409.668
Hs Code.:

Synonyms:2-benzenesulfinyl-1-methyl-3-(4-trimethylsilylmethyl-pent-4-enyl)-1H-indole

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Chemical Property of 2-benzenesulfinyl-1-methyl-3-(4-trimethylsilylmethyl-pent-4-enyl)-1H-indole

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Technology Process of 2-benzenesulfinyl-1-methyl-3-(4-trimethylsilylmethyl-pent-4-enyl)-1H-indole

There total 6 articles about 2-benzenesulfinyl-1-methyl-3-(4-trimethylsilylmethyl-pent-4-enyl)-1H-indole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 74-88-4
methyl iodide

: 712273-18-2
2-benzenesulfinyl-3-(4-trimethylsilylmethyl-pent-4-enyl)-1H-indole

: 712273-30-8
2-benzenesulfinyl-1-methyl-3-(4-trimethylsilylmethyl-pent-4-enyl)-1H-indole

Guidance literature:: With lithium hexamethyldisilazane; In tetrahydrofuran; at 0 ℃; for 3h;
DOI:10.1021/ol0493406 DOI:10.1021/jo050896w

Reference yield:

: 712273-17-1
methyl 4-(2-phenylsulfanyl-1H-indol-3-yl)-butyrate

: 712273-30-8
2-benzenesulfinyl-1-methyl-3-(4-trimethylsilylmethyl-pent-4-enyl)-1H-indole

Guidance literature:: Multi-step reaction with 3 steps

1.1: anhydrous cerium(III) chloride / tetrahydrofuran; pentane / -75 - 20 °C

1.2: 59 percent / silica gel / CH₂Cl₂ / 2 h / 20 °C

2.1: 84 percent / m-chloroperbenzoic acid / CH₂Cl₂ / -90 °C

3.1: 100 percent / lithium hexamethyldisilazide / tetrahydrofuran / 3 h / 0 °C

With cerium(III) chloride; 3-chloro-benzenecarboperoxoic acid; lithium hexamethyldisilazane; In tetrahydrofuran; dichloromethane; pentane;
DOI:10.1021/jo050896w

Reference yield:

: 15591-70-5
methyl 4-(1H-indol-3-yl)butanoate

: 712273-30-8
2-benzenesulfinyl-1-methyl-3-(4-trimethylsilylmethyl-pent-4-enyl)-1H-indole

Guidance literature:: Multi-step reaction with 4 steps

1.1: 97 percent / hydrochloric acid / dioxane / 0.08 h

2.1: anhydrous cerium(III) chloride / tetrahydrofuran; pentane / -75 - 20 °C

2.2: 59 percent / silica gel / CH₂Cl₂ / 2 h / 20 °C

3.1: 84 percent / m-chloroperbenzoic acid / CH₂Cl₂ / -90 °C

4.1: 100 percent / lithium hexamethyldisilazide / tetrahydrofuran / 3 h / 0 °C

With hydrogenchloride; cerium(III) chloride; 3-chloro-benzenecarboperoxoic acid; lithium hexamethyldisilazane; In tetrahydrofuran; 1,4-dioxane; dichloromethane; pentane;
DOI:10.1021/jo050896w