C₆₂H₇₁BrN₄Ni

Base Information

• Chemical Name: C₆₂H₇₁BrN₄Ni
• CAS No.: 262424-49-7
• Molecular Formula: C₆₂H₇₁BrN₄Ni
• Molecular Weight: 1010.87
• Mol file: 262424-49-7.mol

Synonyms:C₆₂H₇₁BrN₄Ni

Chemical Property of C₆₂H₇₁BrN₄Ni

Chemical Property:

Purity/Quality:

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Technology Process of C₆₂H₇₁BrN₄Ni

There total 2 articles about C₆₂H₇₁BrN₄Ni which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

C62H73BrN4 + nickel(II) acetate tetrahydrate (6018-89-9) → 5-bromo-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato nickel(II) (262424-49-7)

Guidance literature:

In N,N-dimethyl-formamide; at 140 ℃; for 2h;

DOI:10.3987/COM-18-S(T)91

Reference yield: 53.0%

[5,10,15-tris(3,5-di-tert-butylphenyl)porphyrinato]nickel(II) (262424-39-5) → 5,10,15-tri(3,5-tBu2C6H3)-Ni(II)-diporphyrin (262424-41-9) + 5,10,15-tri(3,5-tBu2C6H3)-Ni(II)-diporphyrin + Ni(5,10,15-tri(3,5-di-tert-butylphenyl)-20-chloroporphyrin) (262424-40-8) + 5-bromo-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato nickel(II) (262424-49-7)

Guidance literature:

With (BrC₆H₄)3HNSbCl₆; In chloroform; Ni complex was oxidized by the hexachloroantimonate in CHCl3 for 12 h at25°C; the products were sepd. by SEC and then by chromy.(silica gel, hexane/CH2Cl2);

DOI:10.1021/ja0110933

Reference yield: 93.0%

phenoxazine (135-67-1) + 5-bromo-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato nickel(II) (262424-49-7) → C74H79N5NiO

Guidance literature:

With C₄₀H₅₇Cl₂N₃Pd; sodium t-butanolate; In tetrahydrofuran; at 60 ℃; for 13h; Inert atmosphere;

DOI:10.1002/anie.201304794

upstream raw materials:

[5,10,15-tris(3,5-di-tert-butylphenyl)porphyrinato]nickel(II)

nickel(II) acetate tetrahydrate

Downstream raw materials:

C₆₉H₈₀N₄Ni

C₇₂H₇₈N₄NiO

C₉₀H₈₄N₄Ni