C₆₂H₇₂N₄Ni

Base Information

• Chemical Name: C₆₂H₇₂N₄Ni
• CAS No.: 262424-39-5
• Molecular Formula: C₆₂H₇₂N₄Ni
• Molecular Weight: 931.97
• Mol file: 262424-39-5.mol

Synonyms:C₆₂H₇₂N₄Ni

Chemical Property of C₆₂H₇₂N₄Ni

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆₂H₇₂N₄Ni

There total 2 articles about C₆₂H₇₂N₄Ni which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

[5,10,15-tris(3,5-di-tert-butylphenyl)-20-iodoporphyrinato]nickel(II) → [5,10,15-tris(3,5-di-tert-butylphenyl)porphyrinato]nickel(II) (262424-39-5)

Guidance literature:

With hydrogenchloride; In dichloromethane; water; at 20 ℃; for 0.5h; Inert atmosphere;

DOI:10.1002/chem.201502563

Reference yield: 94.0%

5,10,15-tri(3,5-di-tert-butylphenyl)-21H,23H-porphine + nickel(II) acetate tetrahydrate (6018-89-9) → [5,10,15-tris(3,5-di-tert-butylphenyl)porphyrinato]nickel(II) (262424-39-5)

Guidance literature:

In methanol; chloroform; mixed in sat. CH3OH soln. in CHCl3, heated at refluxe for 20 h; washed (H2O), dried (Na2SO4), filtered, evapd., chromy.(SiO2-CHCl3);

DOI:10.1021/jp035412j

Reference yield: 84.0%

[5,10,15-tris(3,5-di-tert-butylphenyl)porphyrinato]nickel(II) (262424-39-5) + 2-bromonaphthalene (580-13-2) → 2,18-di(2-naphthyl)-5,10,15-tris(3,5-di-tert-butylphenyl)Ni(II)porphyrin (1337917-24-4)

Guidance literature:

With palladium diacetate; potassium carbonate; DavePhos; Trimethylacetic acid; In N,N-dimethyl acetamide; at 100 ℃; for 20h; regioselective reaction; Inert atmosphere;

DOI:10.1002/anie.201102318

upstream raw materials:

nickel(II) acetate tetrahydrate

Downstream raw materials:

5,10,15-tri(3,5-tBu₂C₆H₃)-Ni(II)-diporphyrin

Ni(5,10,15-tri(3,5-di-tert-butylphenyl)-20-chloroporphyrin)

5-bromo-10,15,20-tris(3,5-di-tert-butylphenyl)porphyrinato nickel(II)

5,10,15-tris(3,5-di-tert-butylphenyl)-20-formylporphyrin