C₃₂H₄₀N₂O₄Si

Base Information

• Chemical Name: C₃₂H₄₀N₂O₄Si
• CAS No.: 946080-97-3
• Molecular Formula: C₃₂H₄₀N₂O₄Si
• Molecular Weight: 544.766
• Mol file: 946080-97-3.mol

Synonyms:C₃₂H₄₀N₂O₄Si

Chemical Property of C₃₂H₄₀N₂O₄Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₂H₄₀N₂O₄Si

There total 7 articles about C₃₂H₄₀N₂O₄Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

C32H42O4Si (946080-96-2) → C32H40N2O4Si (946080-97-3)

Guidance literature:

With 4-toluenesulfonyl azide; TEA; In acetonitrile; at 20 ℃; for 8h;

DOI:10.1016/j.tetlet.2007.05.046

Reference yield:

1-(tert-butyl-diphenyl-silanyloxymethyl)-cyclohexa-2,5-dienecarbaldehyde (912364-76-2) → C32H40N2O4Si (946080-97-3)

Guidance literature:

Multi-step reaction with 6 steps

1: t-BuOK / tetrahydrofuran / 2 h / -78 - 20 °C

2: 88 percent / Mg / 3 h / 0 - 20 °C

3: KOH / methanol; tetrahydrofuran; H₂O / 8 h / 50 °C

4: tetrahydrofuran / 2 h / 20 °C

5: n-Bu₂Mg / tetrahydrofuran / 28 h / 20 °C

6: 100 percent / TsN₃; TEA / acetonitrile / 8 h / 20 °C

With potassium hydroxide; 4-toluenesulfonyl azide; TEA; dibutylmagnesium; potassium tert-butylate; magnesium; In tetrahydrofuran; methanol; water; acetonitrile; 1: Horner-Wadsworth-Emmons reaction;

DOI:10.1016/j.tetlet.2007.05.046

Reference yield:

[1-(tert-butyl-diphenyl-silanyloxymethyl)-cyclohexa-2,5-dienyl]-methanol (912364-75-1) → C32H40N2O4Si (946080-97-3)

Guidance literature:

Multi-step reaction with 7 steps

1: DMSO; (COCl)2; TEA / CH₂Cl₂ / 1 h / -78 - 20 °C

2: t-BuOK / tetrahydrofuran / 2 h / -78 - 20 °C

3: 88 percent / Mg / 3 h / 0 - 20 °C

4: KOH / methanol; tetrahydrofuran; H₂O / 8 h / 50 °C

5: tetrahydrofuran / 2 h / 20 °C

6: n-Bu₂Mg / tetrahydrofuran / 28 h / 20 °C

7: 100 percent / TsN₃; TEA / acetonitrile / 8 h / 20 °C

With potassium hydroxide; 4-toluenesulfonyl azide; oxalyl dichloride; TEA; dibutylmagnesium; potassium tert-butylate; magnesium; dimethyl sulfoxide; In tetrahydrofuran; methanol; dichloromethane; water; acetonitrile; 1: Swern oxidation / 2: Horner-Wadsworth-Emmons reaction;

DOI:10.1016/j.tetlet.2007.05.046

upstream raw materials:

C₃₂H₄₂O₄Si

1-(tert-butyl-diphenyl-silanyloxymethyl)-cyclohexa-2,5-dienecarbaldehyde

[1-(tert-butyl-diphenyl-silanyloxymethyl)-cyclohexa-2,5-dienyl]-methanol

C₂₈H₃₄O₃Si