912364-76-2

Upstream product

• 74269-63-9 (1-Benzyloxymethyl-cyclohexa-2,5-dienyl)-methanol 
• 912364-75-1 [1-(tert-butyl-diphenyl-silanyloxymethyl)-cyclohexa-2,5-dienyl]-methanol 

Downstream Products

• 868979-51-5 (1-tert-butyldiphenylsilyloxymethyl-2,5-cyclohexadienyl)acetaldehyde 
• 946080-94-0 C₂₈H₃₄O₃Si 
• 912364-74-0 4-[1-(tert-butyl-diphenyl-silanyloxymethyl)-cyclohexa-2,5-dienyl]-2-diazo-3-oxo-butyric acid ethyl ester 
• 912364-77-3 4-[1-(tert-butyl-diphenyl-silanyloxymethyl)-cyclohexa-2,5-dienyl]-3-hydroxy-butyric acid ethyl ester 
• 946080-97-3 C₃₂H₄₀N₂O₄Si 
• 946080-96-2 C₃₂H₄₂O₄Si 

Relevant academic research and scientific papers

Highly enantioselective preparation of tricyclo[4.4.0.05,7]decene derivatives via catalytic asymmetric intramolecular cyclopropanation reactions of α-diazo-β-keto esters

The enantioselective preparation of the tricyclo[4.4.0.05,7]dec-2-ene derivatives via the catalytic asymmetric intramolecular cyclopropanation (CAIMCP) reactions of α-diazo-β-keto esters with excellent ee (95-98% ee) is described. The chiral building blocks reported herein would be versatile intermediates for enantioselective natural products synthesis.

New construction of the bicyclo[3.3.1]nonane system via Lewis acid promoted regioselective ring-opening reaction of the tricyclo[4.4.0.05,7]dec-2-ene derivative

A new access to the bicyclo[3.3.1]nonane system, which is a common structure in a number of polyisoprenylated phloroglucinol derivatives (phloroglucins), has been developed via the Lewis acid promoted regioselective ring-opening reaction of the cyclopropa