2Cl-diPBI

Base Information

• Chemical Name: 2Cl-diPBI
• CAS No.: 1172630-55-5
• Molecular Formula: C₉₆H₇₆Cl₂N₄O₈
• Molecular Weight: 1484.59
• Mol file: 1172630-55-5.mol

Synonyms:2Cl-diPBI

Chemical Property of 2Cl-diPBI

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2Cl-diPBI

There total 2 articles about 2Cl-diPBI which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.0%

N,N'-bis(2,6-diisopropylphenyl)-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid diimide (112078-00-9) → 4Cl-diPBI + 2Cl-diPBI (1172630-55-5)

Guidance literature:

With copper(l) iodide; potassium carbonate; L-proline; In dimethyl sulfoxide; at 75 ℃; for 12h; Inert atmosphere;

DOI:10.1021/ol901168k

Reference yield:

N,N'-bis(2,6-diisopropylphenyl)-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid diimide (112078-00-9) → 2Cl-diPBI (1172630-55-5)

Guidance literature:

With copper(l) iodide; potassium carbonate; L-proline; In dimethyl sulfoxide; at 75 ℃; for 10h; Inert atmosphere;

Reference yield: 92.0%

2Cl-diPBI (1172630-55-5) + p-aminoethylbenzoate (94-09-7) → C105H85N5O10 (1172630-56-6)

Guidance literature:

With potassium tert-butylate; palladium diacetate; tricyclohexylphosphine; In toluene; at 110 ℃; for 5h; Inert atmosphere;

DOI:10.1021/ol901168k

upstream raw materials:

N,N'-bis(2,6-diisopropylphenyl)-1,6,7,12-tetrachloroperylene-3,4:9,10-tetracarboxylic acid diimide

Downstream raw materials:

C₁₀₅H₈₅N₅O₁₀

C₁₄₀H₁₀₃N₉O₈Pd

C₁₁₄H₉₀N₆O₈

Refernces

• 1、 Zhen, Yonggang,Qian, Hualei,Xiang, Junfeng,Qu, Jianqiang,Wang, Zhaohui. "Highly regiospecific synthetic approach to monobay-functionalized perylene bisimide and Di(perylene bisimide)". supporting information; experimental part. p. 3084 - 3087. Retrieved 2009/12/05.