1-[2-(2-Methyl-cyclohexa-1,4-dienyl)-ethyl]-cyclohexa-2,4-dienecarboxylic acid methyl ester

Base Information

Chemical Name:1-[2-(2-Methyl-cyclohexa-1,4-dienyl)-ethyl]-cyclohexa-2,4-dienecarboxylic acid methyl ester
CAS No.:110511-81-4
Molecular Formula:C₁₇H₂₂O₂
Molecular Weight:258.36
Hs Code.:

Synonyms:1-[2-(2-Methyl-cyclohexa-1,4-dienyl)-ethyl]-cyclohexa-2,4-dienecarboxylic acid methyl ester

Suppliers and Price of 1-[2-(2-Methyl-cyclohexa-1,4-dienyl)-ethyl]-cyclohexa-2,4-dienecarboxylic acid methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-[2-(2-Methyl-cyclohexa-1,4-dienyl)-ethyl]-cyclohexa-2,4-dienecarboxylic acid methyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-[2-(2-Methyl-cyclohexa-1,4-dienyl)-ethyl]-cyclohexa-2,4-dienecarboxylic acid methyl ester

There total 2 articles about 1-[2-(2-Methyl-cyclohexa-1,4-dienyl)-ethyl]-cyclohexa-2,4-dienecarboxylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 110511-79-0
2-(2-methylcyclohexa-1,4-dien-1-yl)ethan-1-ol

: 110511-81-4
1-[2-(2-Methyl-cyclohexa-1,4-dienyl)-ethyl]-cyclohexa-2,4-dienecarboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 93 percent / Ph₃P, imidazole, iodine / diethyl ether; acetonitrile / 0.5 h / 25 °C

2: 1.) LDA, 2.) hexamethylphosphoric triamide / 1.) THF, -78 deg C, 1 h, 2.) THF, -78 deg C, 5 h; -78 to -20 deg C, 9 h

With 1H-imidazole; N,N,N,N,N,N-hexamethylphosphoric triamide; iodine; triphenylphosphine; lithium diisopropyl amide; In diethyl ether; acetonitrile;
DOI:10.1021/ja00254a051

Reference yield:

: 54162-19-5
2,4-Cyclohexadien-1-carbonsaeure-methylester

: 110511-80-3
1-(2-Iodo-ethyl)-2-methyl-cyclohexa-1,4-diene

: 110511-81-4
1-[2-(2-Methyl-cyclohexa-1,4-dienyl)-ethyl]-cyclohexa-2,4-dienecarboxylic acid methyl ester

Guidance literature:: With N,N,N,N,N,N-hexamethylphosphoric triamide; lithium diisopropyl amide; Yield given. Multistep reaction; 1.) THF, -78 deg C, 1 h, 2.) THF, -78 deg C, 5 h; -78 to -20 deg C, 9 h;
DOI:10.1021/ja00254a051