bis(1'-mesitylthiolatoferrocenyl)disulfane

Base Information

• Chemical Name: bis(1'-mesitylthiolatoferrocenyl)disulfane
• CAS No.: 326887-77-8
• Molecular Formula: C₃₈H₃₈Fe₂S₄
• Molecular Weight: 734.678
• Mol file: 326887-77-8.mol

Synonyms:bis(1'-mesitylthiolatoferrocenyl)disulfane

Chemical Property of bis(1'-mesitylthiolatoferrocenyl)disulfane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of bis(1'-mesitylthiolatoferrocenyl)disulfane

There total 1 articles about bis(1'-mesitylthiolatoferrocenyl)disulfane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

1,2,3-trithia{3}ferrocenophane + mesityllithium (5806-59-7) → bis(1'-mesitylthiolatoferrocenyl)disulfane (326887-77-8)

Guidance literature:

In tetrahydrofuran; under N2 atm. to soln. 1,2,3-trithia-(3)ferrocenophane in THF at -78°C mesityllithium in THF was added and stirred at room temp. overnight; water was added, organic layer was dried over MgSO4 and evapd. to dryness, column chromy. on alumina (CH2Cl2-hexane 2:8); elem. anal.;

DOI:10.1039/b306982f

Reference yield: 93.0%

bis(benzonitrile)dichloroplatinum(II) (14873-63-3,15617-19-3,51921-56-3) + bis(1'-mesitylthiolatoferrocenyl)disulfane (326887-77-8) + lithium triethylborohydride (22560-16-3) → bis[1'-(mesitylthio)ferrocene-1-(μ-thiolato)]bisplatinum(II)dichloride (670218-68-5)

Guidance literature:

In toluene; under N2 atm. to soln. di(1'-(mesitylthio)ferrocene)disulfide in THF Li(HBEt3) in THF was added and stirred for 1.5 h, volatiles were removed invacuo, residue was dissolved in toluene, soln. PtCl2(PhCN)2 in toluene was added at 60°C, 16 h; ppt. was filtered, washed with hot toluene, filtrate was evapd., residuewas suspended in hot hexane, recrystn. from CH2Cl2-hexane (1:1); elem. anal.;

DOI:10.1039/b306982f

Reference yield: 88.0%

bis(1'-mesitylthiolatoferrocenyl)disulfane (326887-77-8) + lithium triethylborohydride (22560-16-3) → 1'-(mesitylthio)ferrocene-1-thiol (326887-80-3)

Guidance literature:

With aq.KOH; HCl; In tetrahydrofuran; mixed, stirred for 1,5 h; solv. removed (vac.), dissolved (diethyl ether), poured into 1% KOH, treated with conc.HCl, extd.(diethyl ether), organic layer dried (MgSO4), evapd., NMR, MAS;

DOI:10.1039/b007511f

upstream raw materials:

mesityllithium

Downstream raw materials:

1'-(mesitylthio)ferrocene-1-thiol

bis[1'-(mesitylthio)ferrocene-1-(μ-thiolato)]bisplatinum(II)dichloride

1-(methylthio)-1'-(mesitylthio)ferrocene

bis(tetrahydrofuran)dichloro[1'-(mesitylthio)ferrocene-1-(thiolato)]chromium(III)