(4E,8E)-Dodeca-4,8-dienedial

Base Information

• Chemical Name: (4E,8E)-Dodeca-4,8-dienedial
• CAS No.: 60391-93-7
• Molecular Formula: C12H18 O2
• Molecular Weight: 194.274
• European Community (EC) Number: 262-215-8,259-584-2
• DSSTox Substance ID: DTXSID301310435
• Nikkaji Number: J248.766G,J266.968D,J268.187K
• Mol file: 60391-93-7.mol

Synonyms:(4E,8E)-Dodeca-4,8-dienedial;Dodeca-4,8-dienedial;60391-93-7;EINECS 259-584-2;EINECS 262-215-8;55303-96-3;(4E,8E)-4,8-Dodecadienedial;4,8-Dodecadienedial;SCHEMBL10830824;(4E,8Z)-4,8-Dodecadienedial;DTXSID301310435;(E,E)-4,8-Dodecadien-1,12-dialdehyd

Chemical Property of (4E,8E)-Dodeca-4,8-dienedial

Chemical Property:

• PSA: 34.14000
• LogP: 2.83720
• XLogP3: 1.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 9
• Exact Mass: 194.130679813
• Heavy Atom Count: 14
• Complexity: 171

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C(CC=CCCC=O)C=CCCC=O
• Isomeric SMILES: C(/C=C/CCC=O)C/C=C/CCC=O

Technology Process of (4E,8E)-Dodeca-4,8-dienedial

There total 4 articles about (4E,8E)-Dodeca-4,8-dienedial which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

(4E,8E)-dodeca-4,8-diene-1,12-diol (131392-77-3) → (4E,8E)-dodeca-4,8-dienedial (60391-93-7)

Guidance literature:

With sodium periodate; In dichloromethane; acetone; for 2h; Ambient temperature;

DOI:10.1021/ja981302s

Reference yield: 92.0%

(5E,9E)-(1R,2R)-Cyclododeca-5,9-diene-1,2-diol (5202-25-5,15786-26-2,29118-70-5,122674-42-4,122674-45-7) → (4E,8E)-dodeca-4,8-dienedial (60391-93-7)

Guidance literature:

With sodium periodate; In tetrahydrofuran; water;

DOI:10.1021/ja9049959

Reference yield: 59.0%

(1E,5E,9E)-cyclododeca-1,5,9-triene (676-22-2) → (4E,8E)-dodeca-4,8-dienedial (60391-93-7)

Guidance literature:

(1E,5E,9E)-cyclododeca-1,5,9-triene; With osmium(VIII) oxide; 4-methylmorpholine N-oxide; Inert atmosphere;

With sodium periodate; silica gel; Inert atmosphere;

DOI:10.1039/b813201a

upstream raw materials:

(1E,5E,9E)-cyclododeca-1,5,9-triene

(4E,8E)-dodeca-4,8-diene-1,12-diol

trans,trans-5,9-Cyclododecadien-1,2-diol

(5E,9E)-(1R,2R)-Cyclododeca-5,9-diene-1,2-diol

Downstream raw materials:

(5E,9E)-(1R,2S)-Cyclododeca-5,9-diene-1,2-diol

(5E,9E)-(1R,2R)-Cyclododeca-5,9-diene-1,2-diol

C₄₄H₅₈O₂Si₂

cis-4-(tert-butyldiphenylsiloxy)-1-{5-[4-(tert-butyldiphenylsiloxy)-1-hydroxybutyl]tetrahydrofuran-2-yl}butan-1-ol