methyl 2,3-di-O-benzoyl-4-O-(2-nitrophenyl)dichloroacetyl-1-O-trichloroacetimidoyl-α-D-glucopyranuronate

Base Information

Chemical Name:methyl 2,3-di-O-benzoyl-4-O-(2-nitrophenyl)dichloroacetyl-1-O-trichloroacetimidoyl-α-D-glucopyranuronate
CAS No.:1418273-83-2
Molecular Formula:C₃₁H₂₃Cl₅N₂O₁₂
Molecular Weight:792.795
Hs Code.:

Synonyms:methyl 2,3-di-O-benzoyl-4-O-(2-nitrophenyl)dichloroacetyl-1-O-trichloroacetimidoyl-α-D-glucopyranuronate

Suppliers and Price of methyl 2,3-di-O-benzoyl-4-O-(2-nitrophenyl)dichloroacetyl-1-O-trichloroacetimidoyl-α-D-glucopyranuronate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 2,3-di-O-benzoyl-4-O-(2-nitrophenyl)dichloroacetyl-1-O-trichloroacetimidoyl-α-D-glucopyranuronate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 2,3-di-O-benzoyl-4-O-(2-nitrophenyl)dichloroacetyl-1-O-trichloroacetimidoyl-α-D-glucopyranuronate

There total 3 articles about methyl 2,3-di-O-benzoyl-4-O-(2-nitrophenyl)dichloroacetyl-1-O-trichloroacetimidoyl-α-D-glucopyranuronate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1418273-73-0
methyl [4-methoxyphenyl 2,3-di-O-benzoyl-4-O-(2-nitrophenyl)acetyl-β-D-glucopyranosid]uronate

: 545-06-2
trichloroacetonitrile

: methyl 2,3-di-O-benzoyl-4-O-(2-nitrophenyl)-(S)-chloroacetyl-1-O-trichloroacetimidoyl-α-D-glucopyranuronate

: 1418273-83-2
methyl 2,3-di-O-benzoyl-4-O-(2-nitrophenyl)dichloroacetyl-1-O-trichloroacetimidoyl-α-D-glucopyranuronate

: methyl 2,3-di-O-benzoyl-4-O-(2-nitrophenyl)-(R)-chloroacetyl-1-O-trichloroacetimidoyl-α-D-glucopyranuronate

Guidance literature:: methyl [4-methoxyphenyl 2,3-di-O-benzoyl-4-O-(2-nitrophenyl)acetyl-β-D-glucopyranosid]uronate; With 1,8-diazabicyclo[5.4.0]undec-7-ene; trichloroacetonitrile; In dichloromethane; at 20 ℃; for 3.5h;

With ammonium cerium (IV) nitrate; In water; toluene; acetonitrile; at 20 ℃; for 0.25h;

trichloroacetonitrile; With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; at 20 ℃; for 0.5h; Overall yield = 266 mg;
DOI:10.1016/j.carres.2012.11.003

Reference yield:

: 181584-02-1
methyl (4-methoxyphenyl 2,3-di-O-benzoyl-β-D-glucopyranosid)uronate

: methyl 2,3-di-O-benzoyl-4-O-(2-nitrophenyl)-(S)-chloroacetyl-1-O-trichloroacetimidoyl-α-D-glucopyranuronate

: 1418273-83-2
methyl 2,3-di-O-benzoyl-4-O-(2-nitrophenyl)dichloroacetyl-1-O-trichloroacetimidoyl-α-D-glucopyranuronate

: methyl 2,3-di-O-benzoyl-4-O-(2-nitrophenyl)-(R)-chloroacetyl-1-O-trichloroacetimidoyl-α-D-glucopyranuronate

Guidance literature:: Multi-step reaction with 2 steps

1.1: dmap; dicyclohexyl-carbodiimide / dichloromethane / 1 h / 20 °C

2.1: trichloroacetonitrile; 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 3.5 h / 20 °C

2.2: 0.25 h / 20 °C

2.3: 0.5 h / 20 °C

With dmap; 1,8-diazabicyclo[5.4.0]undec-7-ene; trichloroacetonitrile; dicyclohexyl-carbodiimide; In dichloromethane;
DOI:10.1016/j.carres.2012.11.003

Reference yield:

: 3740-52-1
2-(2-nitrophenyl)acetic acid

: methyl 2,3-di-O-benzoyl-4-O-(2-nitrophenyl)-(S)-chloroacetyl-1-O-trichloroacetimidoyl-α-D-glucopyranuronate

: 1418273-83-2
methyl 2,3-di-O-benzoyl-4-O-(2-nitrophenyl)dichloroacetyl-1-O-trichloroacetimidoyl-α-D-glucopyranuronate

: methyl 2,3-di-O-benzoyl-4-O-(2-nitrophenyl)-(R)-chloroacetyl-1-O-trichloroacetimidoyl-α-D-glucopyranuronate

Guidance literature:: Multi-step reaction with 2 steps

1.1: dmap; dicyclohexyl-carbodiimide / dichloromethane / 1 h / 20 °C

2.1: trichloroacetonitrile; 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 3.5 h / 20 °C

2.2: 0.25 h / 20 °C

2.3: 0.5 h / 20 °C

With dmap; 1,8-diazabicyclo[5.4.0]undec-7-ene; trichloroacetonitrile; dicyclohexyl-carbodiimide; In dichloromethane;
DOI:10.1016/j.carres.2012.11.003