N,N'-dimethyl-3-anilinocarbazole

Base Information

• Chemical Name: N,N'-dimethyl-3-anilinocarbazole
• CAS No.: 86885-08-7
• Molecular Formula: C₂₀H₁₈N₂
• Molecular Weight: 286.376
• Mol file: 86885-08-7.mol

Synonyms:N,N'-dimethyl-3-anilinocarbazole

Chemical Property of N,N'-dimethyl-3-anilinocarbazole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N'-dimethyl-3-anilinocarbazole

There total 6 articles about N,N'-dimethyl-3-anilinocarbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + (9-Methyl-9H-carbazol-3-yl)-phenyl-amine (180331-85-5) → 9-methyl-3-(N-methylanilino)carbazole (86885-08-7)

Guidance literature:

With sodium cyanoborohydride; In acetic acid; acetonitrile; for 2.5h;

DOI:10.1080/00397919608004606

Reference yield: 12.0%

N,N'-dimethyl-N,N'-diphenyl-1,4-phenylenediamine (17754-68-6) → N,N'-dimethyl-3-anilinocarbazole (86885-08-7)

Guidance literature:

With oxygen; In methyl cyclohexane; for 1.5h; Irradiation;

DOI:10.1021/ja00358a014

Reference yield:

N,N'-diphenyl-1,4-phenylenediamine (74-31-7,943443-44-5) → N,N'-dimethyl-3-anilinocarbazole (86885-08-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 5 percent / 100 deg C (30 min), ->180 deg C (1 h), 180 deg C, 30 min

2: 12 percent / O₂ / methylcyclohexane / 1.5 h / Irradiation

With oxygen; In methyl cyclohexane;

DOI:10.1021/ja00358a014

upstream raw materials:

N,N'-dimethyl-N,N'-diphenyl-1,4-phenylenediamine

N,N'-diphenyl-1,4-phenylenediamine

formaldehyd

(9-Methyl-9H-carbazol-3-yl)-phenyl-amine

Downstream raw materials:

N,N'-Dimethyl-5,11-dihydroindolo<3,2-b>carbazol

Refernces

• 1、 Chakrabarty, Manas,Batabyal, Archana. "An expedient synthesis of 5,11-dimethylindolo[3,2-b]-carbazole, a potent ligand for the receptor for TCDD". . p. 3015 - 3023. Retrieved 2007/10/03.