(η(2)-1,2-bis(diphenylphosphino)ethane)(η(5)-pentamethylcyclopentadienyl)Fe-C.tplbond.C-p-(C5H4N)

Base Information

Chemical Name:(η(2)-1,2-bis(diphenylphosphino)ethane)(η(5)-pentamethylcyclopentadienyl)Fe-C.tplbond.C-p-(C5H4N)
CAS No.:221243-88-5
Molecular Formula:C₄₃H₄₃FeNP₂
Molecular Weight:691.616
Hs Code.:

Synonyms:(η(2)-1,2-bis(diphenylphosphino)ethane)(η(5)-pentamethylcyclopentadienyl)Fe-C.tplbond.C-p-(C5H4N)

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Chemical Property of (η(2)-1,2-bis(diphenylphosphino)ethane)(η(5)-pentamethylcyclopentadienyl)Fe-C.tplbond.C-p-(C5H4N)

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Technology Process of (η(2)-1,2-bis(diphenylphosphino)ethane)(η(5)-pentamethylcyclopentadienyl)Fe-C.tplbond.C-p-(C5H4N)

There total 3 articles about (η(2)-1,2-bis(diphenylphosphino)ethane)(η(5)-pentamethylcyclopentadienyl)Fe-C.tplbond.C-p-(C5H4N) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 1120-87-2
4-bromopyridin

: (η(2)-1,2-bis(diphenylphosphino)ethane)(η(5)-pentamethylcyclopentadienyl)Fe-C.tplbond.CH

: 221243-88-5
(η(2)-1,2-bis(diphenylphosphino)ethane)(η(5)-pentamethylcyclopentadienyl)Fe-C.tplbond.C-p-(C5H4N)

Guidance literature:: With PdCl₂(PPh₃)2; copper iodide; di-iso-propylamine; In further solvent(s); Ar-atmosphere; refluxing Fe-complex with 0.1 equiv. of PdCl2(PPh3)2, 0.2 equiv. of copper iodide and with pyridine derivative for 12 h (in diisopropylamine); evapn. (reduced pressure), extn. into PhMe, filtration (Celite), evapn., washing (pentane, MeCN, -40°C); can be recrystallized (PhMe/pentane);
DOI:10.1016/S0022-328X(98)00961-9

Reference yield: 69.0%

: (η(2)-1,2-bis(diphenylphosphino)ethane)(η(5)-pentamethylcyclopentadienyl)Fe-C.tplbond.CH

: 19524-06-2
4-bromopyridine hydrochloride

: 221243-88-5
(η(2)-1,2-bis(diphenylphosphino)ethane)(η(5)-pentamethylcyclopentadienyl)Fe-C.tplbond.C-p-(C5H4N)

Guidance literature:: With catalyst: PdCl₂(PPh₃)2/CuI; In further solvent(s); Ar-atmosphere; refluxing in HN(i-Pr)2 for 12 h; distn. off of solvent (low temp.), extn. into PhMe, filtration (Celite),evapn., washing (pentane, -40°C; then MeCN, -20°C), dryin g (vac.); can be recrystallized (PhMe/pentane); elem. anal.;
DOI:10.1016/s0020-1693(99)00135-8