rac-bis((RR,SS)-o-phenylenebis(methylphenylphosphine))nickel(II) hexafluorophosphate

Base Information

Chemical Name:rac-bis((RR,SS)-o-phenylenebis(methylphenylphosphine))nickel(II) hexafluorophosphate
CAS No.:77059-51-9
Molecular Formula:C₄₀H₄₀NiP₄*2F₆P
Molecular Weight:993.271
Hs Code.:

Synonyms:rac-bis((RR,SS)-o-phenylenebis(methylphenylphosphine))nickel(II) hexafluorophosphate

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Chemical Property of rac-bis((RR,SS)-o-phenylenebis(methylphenylphosphine))nickel(II) hexafluorophosphate

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Technology Process of rac-bis((RR,SS)-o-phenylenebis(methylphenylphosphine))nickel(II) hexafluorophosphate

There total 1 articles about rac-bis((RR,SS)-o-phenylenebis(methylphenylphosphine))nickel(II) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

: ammonium hexafluorophosphate

: 122331-49-1
(R*,R*)-(+/-)-1,2-phenylenebis(methylphenylphosphine)

: 6018-89-9
nickel(II) acetate tetrahydrate

: 77059-53-1
meso-((RR)-o-phenylenebis(methylphenylphosphine))((SS)-o-phenylenebis(methylphenylphosphine))nickel(II) hexafluorophosphate

: 77059-51-9
rac-bis((RR,SS)-o-phenylenebis(methylphenylphosphine))nickel(II) hexafluorophosphate

Guidance literature:: In ethanol; suspn. nickel(II) acetate, (RR,SS)-diars and NH4PF6 in ethanol heated under reflux with stirring for 15 min; React.Mixt. evapd., residue heated in vacuo (100°C, 20mmHg), solid extd. with boiling methanol: residue recrystd. from MeCN-Et2O - meso-isomer, filtrate concd. and cooled - rac-isomer;elem. anal.;

Reference yield: 99.0%

: 77059-51-9
rac-bis((RR,SS)-o-phenylenebis(methylphenylphosphine))nickel(II) hexafluorophosphate

: 77059-61-1
rac-chlorobis((RR,SS)-o-phenylenebis(methylphenylphosphine))nickel(II) hexafluorophosphate

Guidance literature:: With lithium chloride; In acetone; suspn. rac-bis-hexafluorophosphate and LiCl in acetone stirred until reagents dissolved; react. mixt. diluted with diethyl ether, ppt. collected, washed with water, dried and recrystd. from acetone-diethyl ether; elem. anal.;