(2-methyl-5-tert-butylphenyl) 2-O-benzyl-4,6-O-(p-methoxybenzylidene)-3-O-(2-naphthalenylmethyl)-1-thia-α-D-mannopyranoside

Base Information

Chemical Name:(2-methyl-5-tert-butylphenyl) 2-O-benzyl-4,6-O-(p-methoxybenzylidene)-3-O-(2-naphthalenylmethyl)-1-thia-α-D-mannopyranoside
CAS No.:1442422-75-4
Molecular Formula:C₄₃H₄₆O₆S
Molecular Weight:690.901
Hs Code.:

Synonyms:(2-methyl-5-tert-butylphenyl) 2-O-benzyl-4,6-O-(p-methoxybenzylidene)-3-O-(2-naphthalenylmethyl)-1-thia-α-D-mannopyranoside

Suppliers and Price of (2-methyl-5-tert-butylphenyl) 2-O-benzyl-4,6-O-(p-methoxybenzylidene)-3-O-(2-naphthalenylmethyl)-1-thia-α-D-mannopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (2-methyl-5-tert-butylphenyl) 2-O-benzyl-4,6-O-(p-methoxybenzylidene)-3-O-(2-naphthalenylmethyl)-1-thia-α-D-mannopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2-methyl-5-tert-butylphenyl) 2-O-benzyl-4,6-O-(p-methoxybenzylidene)-3-O-(2-naphthalenylmethyl)-1-thia-α-D-mannopyranoside

There total 6 articles about (2-methyl-5-tert-butylphenyl) 2-O-benzyl-4,6-O-(p-methoxybenzylidene)-3-O-(2-naphthalenylmethyl)-1-thia-α-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₃₆H₄₀O₆S

: 100-39-0
benzyl bromide

: 1442422-75-4
(2-methyl-5-tert-butylphenyl) 2-O-benzyl-4,6-O-(p-methoxybenzylidene)-3-O-(2-naphthalenylmethyl)-1-thia-α-D-mannopyranoside

Guidance literature:: C₃₆H₄₀O₆S; With sodium hydride; In N,N-dimethyl-formamide; at 0 ℃; for 0.166667h; Inert atmosphere;

benzyl bromide; With cesium fluoride; In N,N-dimethyl-formamide; at 20 ℃; Inert atmosphere;
DOI:10.1016/j.tet.2013.04.094

Reference yield:

: 1379519-57-9
(2-methyl-5-tert-butylphenyl) 2,3,4,6-tetra-O-acetyl-1-thia-α-D-mannopyranoside

: 1442422-75-4
(2-methyl-5-tert-butylphenyl) 2-O-benzyl-4,6-O-(p-methoxybenzylidene)-3-O-(2-naphthalenylmethyl)-1-thia-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1.1: sodium methylate / methanol / 20 °C / Inert atmosphere

2.1: toluene-4-sulfonic acid / N,N-dimethyl-formamide / 60 °C / Inert atmosphere

3.1: di(n-butyl)tin oxide / toluene / Inert atmosphere; Reflux

3.2: 20 h / 20 °C / Inert atmosphere

4.1: sodium hydride / N,N-dimethyl-formamide / 0.17 h / 0 °C / Inert atmosphere

4.2: 20 °C / Inert atmosphere

With sodium methylate; sodium hydride; di(n-butyl)tin oxide; toluene-4-sulfonic acid; In methanol; N,N-dimethyl-formamide; toluene;
DOI:10.1016/j.tet.2013.04.094

Reference yield:

: 1361016-58-1
(2-methyl-5-tert-butylphenyl) 1-thio-α-D-mannopyranoside

: 1442422-75-4
(2-methyl-5-tert-butylphenyl) 2-O-benzyl-4,6-O-(p-methoxybenzylidene)-3-O-(2-naphthalenylmethyl)-1-thia-α-D-mannopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1.1: toluene-4-sulfonic acid / N,N-dimethyl-formamide / 60 °C / Inert atmosphere

2.1: di(n-butyl)tin oxide / toluene / Inert atmosphere; Reflux

2.2: 20 h / 20 °C / Inert atmosphere

3.1: sodium hydride / N,N-dimethyl-formamide / 0.17 h / 0 °C / Inert atmosphere

3.2: 20 °C / Inert atmosphere

With sodium hydride; di(n-butyl)tin oxide; toluene-4-sulfonic acid; In N,N-dimethyl-formamide; toluene;
DOI:10.1016/j.tet.2013.04.094