dibutyl-lambda~2~-stannane - acetic acid (1:1)

Base Information

• Chemical Name: dibutyl-lambda~2~-stannane - acetic acid (1:1)
• CAS No.: 54460-73-0
• Molecular Formula: C20H44O4Sn2
• Molecular Weight: 583.971
• Mol file: 54460-73-0.mol

Synonyms:

Chemical Property of dibutyl-lambda~2~-stannane - acetic acid (1:1)

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of dibutyl-lambda~2~-stannane - acetic acid (1:1)

There total 4 articles about dibutyl-lambda~2~-stannane - acetic acid (1:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dibutylstannane (1002-53-5) + acetic acid (64-19-7,77671-22-8) → 1,2-bis(acetyloxy)tetrabutyldistannane (54460-73-0) + dibutyltin diacetate (1067-33-0)

Guidance literature:

In not given; reaction at room temperature;;

DOI:10.1021/ja01507a048 DOI:10.1021/jo01050a035 DOI:10.1021/jo01049a064

Reference yield:

dibutylstannane (1002-53-5) + dibutyltin diacetate (1067-33-0) → 1,2-bis(acetyloxy)tetrabutyldistannane (54460-73-0)

Guidance literature:

In not given;

DOI:10.1021/ja01507a048 DOI:10.1021/jo01050a035

Reference yield:

1,2-dichlorodiacetoxystannane (1000-23-3,37960-24-0,37766-24-8) + dibutylstannane (1002-53-5) → 1,2-bis(acetyloxy)tetrabutyldistannane (54460-73-0)

Guidance literature:

With sodium acetate; bis-triphenylphosphine-palladium(II) chloride; In pentane; in a Schlenk tube under N2 mixing of Sn-compds. in pentane, after 15 min addn. of catalyst and stirring at room temp. for 2 h, addn. of a 5-fold excess of Na-acetate (or Ag- or K-salts), stirring for 1 h; filtn., evapn. of solvent, purity >95%;

DOI:10.1021/om00015a042

upstream raw materials:

dibutylstannane

acetic acid

dibutyltin diacetate

1,2-dichlorodiacetoxystannane

Refernces