superoxo(tetrakis(2,6-difluorophenyl)porphyrinato)(tetrahydrofuran)iron(III)

Base Information

• Chemical Name: superoxo(tetrakis(2,6-difluorophenyl)porphyrinato)(tetrahydrofuran)iron(III)
• CAS No.: 379217-58-0
• Molecular Formula: C₄₈H₂₈F₈FeN₄O₃
• Molecular Weight: 916.61
• Mol file: 379217-58-0.mol

Synonyms:superoxo(tetrakis(2,6-difluorophenyl)porphyrinato)(tetrahydrofuran)iron(III)

Chemical Property of superoxo(tetrakis(2,6-difluorophenyl)porphyrinato)(tetrahydrofuran)iron(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of superoxo(tetrakis(2,6-difluorophenyl)porphyrinato)(tetrahydrofuran)iron(III)

There total 2 articles about superoxo(tetrakis(2,6-difluorophenyl)porphyrinato)(tetrahydrofuran)iron(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(tetrakis(2,6-difluorophenyl)porphyrinato)bis(tetrahydrofuran)iron(II) (593246-45-8) + oxygen (80937-33-3) → superoxo(tetrakis(2,6-difluorophenyl)porphyrinato)(tetrahydrofuran)iron(III) (379217-58-0)

Guidance literature:

In dichloromethane; acetonitrile; O2 bubbled through soln. of Fe complex in CH2Cl2-MeCN at -80°C; monitored by UV-vis spectra; excess O2 removed by vac.-Ar cycling;

DOI:10.1021/ja036632d

Reference yield:

tetrahydrofuran (109-99-9,24979-97-3,77392-70-2) + [(tetrakis(2,6-difluorophenyl)porphyrinate)FeIII(O22?)]? (648898-73-1) → superoxo(tetrakis(2,6-difluorophenyl)porphyrinato)(tetrahydrofuran)iron(III) (379217-58-0)

Guidance literature:

With tris(p-bromophenylammoniumyl) hexachloroantimonate; Equilibrium constant; Kinetics; Inert atmosphere; Schlenk technique;

DOI:10.1021/jacs.9b12571

Reference yield:

superoxo(tetrakis(2,6-difluorophenyl)porphyrinato)(tetrahydrofuran)iron(III) (379217-58-0) → hydroxo(meso-tetrakis(2,6-difluorophenyl)porphirinato)iron(III) (98716-00-8)

Guidance literature:

With 2,4-di-tert-butylphenol; NO; In tetrahydrofuran; -80°C;

DOI:10.1021/ja904832j

upstream raw materials:

(tetrakis(2,6-difluorophenyl)porphyrinato)bis(tetrahydrofuran)iron(II)

oxygen

tetrahydrofuran

[(tetrakis(2,6-difluorophenyl)porphyrinate)Fe^III(O₂^2?)]^?

Downstream raw materials:

cobaltocenium peroxo(tetrakis(2,6-difluorophenyl)porphyrinato)iron(III)

hydroxo(meso-tetrakis(2,6-difluorophenyl)porphirinato)iron(III)

[Fe(NO₃)[tetrakis(2,6-difluorophenyl)porphyrinate^(2-)]]