cobaltocenium peroxo(tetrakis(2,6-difluorophenyl)porphyrinato)iron(III)

Base Information

• Chemical Name: cobaltocenium peroxo(tetrakis(2,6-difluorophenyl)porphyrinato)iron(III)
• CAS No.: 648898-74-2
• Molecular Formula: C₁₀H₁₀Co*C₄₄H₂₀F₈FeN₄O₂
• Molecular Weight: 1033.69
• Mol file: 648898-74-2.mol

Synonyms:

Chemical Property of cobaltocenium peroxo(tetrakis(2,6-difluorophenyl)porphyrinato)iron(III)

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cobaltocenium peroxo(tetrakis(2,6-difluorophenyl)porphyrinato)iron(III)

There total 1 articles about cobaltocenium peroxo(tetrakis(2,6-difluorophenyl)porphyrinato)iron(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cobaltocene (1277-43-6,78206-33-4) + superoxo(tetrakis(2,6-difluorophenyl)porphyrinato)(tetrahydrofuran)iron(III) (379217-58-0) → cobaltocenium peroxo(tetrakis(2,6-difluorophenyl)porphyrinato)iron(III) (648898-74-2)

Guidance literature:

In dichloromethane; acetonitrile; Co complex (1 equiv.) added to soln. of Fe complex in CH2Cl2-MeCN; monitored by UV-vis spectra;

DOI:10.1021/ja036632d

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + cobaltocenium peroxo(tetrakis(2,6-difluorophenyl)porphyrinato)iron(III) (648898-74-2) → [meso-5,10,15,20-tetrakis-(2,6-difluorophenyl)porhpyrinato]-iron(III) chloride (99038-25-2,221335-24-6)

Guidance literature:

In not given; byproducts: H2O2;

DOI:10.1021/ja036632d

Reference yield:

[Cu(tris(2-pyridylmethyl)amine)(CH3CN)](ClO4)2 + cobaltocenium peroxo(tetrakis(2,6-difluorophenyl)porphyrinato)iron(III) (648898-74-2) → cobaltocenium perchlorate + [(tetrakis(2,6-difluorophenyl)porphyrinato)Fe(III)(μ-peroxo)Cu(II)(tris(2-pyridylmethyl)amine)](ClO4)

Guidance literature:

In tetrahydrofuran; Cu complex added to soln. of Fe complex in THF at -95°C; pptd. with heptane; (CoCp2)(ClO4) copptd. with Fe-Co complex; detd. by UV-vis and (1)H NMR spectra;

DOI:10.1021/ja036632d

upstream raw materials:

cobaltocene

superoxo(tetrakis(2,6-difluorophenyl)porphyrinato)(tetrahydrofuran)iron(III)

Downstream raw materials:

[meso-5,10,15,20-tetrakis-(2,6-difluorophenyl)porhpyrinato]-iron(III) chloride