C₂H₁₁B₁₀(C₆H₉)

Base Information

• Chemical Name: C₂H₁₁B₁₀(C₆H₉)
• CAS No.: 127085-62-5
• Molecular Formula: C₈H₂₀B₁₀
• Molecular Weight: 224.357
• Mol file: 127085-62-5.mol

Synonyms:C₂H₁₁B₁₀(C₆H₉)

Chemical Property of C₂H₁₁B₁₀(C₆H₉)

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of C₂H₁₁B₁₀(C₆H₉)

There total 3 articles about C₂H₁₁B₁₀(C₆H₉) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

C9H18B10O3S + cyclohexene (110-83-8) → C2H11B10(C6H9) (127085-62-5)

Guidance literature:

With lithium hexamethyldisilazane; In cyclohexane; at 20 ℃; for 0.0333333h; chemoselective reaction; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.orglett.1c00649

Reference yield: 67.0%

bis(triphenylphosphine)nickel(II) chloride (14264-16-5,53996-95-5,62075-39-2,39716-73-9) + n-butyllithium (109-72-8,29786-93-4) + 1,2-dicarba-closo-dodecaborane(12) (16872-09-6) + cyclohexene (110-83-8) → C2H11B10(C6H9) (127085-62-5)

Guidance literature:

In tetrahydrofuran; Ni complex was added to soln. Li2C2B10H10 in THF (from C2B10H12 and n-BuLi), mixt. was stirred at room temp. for 0.5 h, alkene was added, mixt. was heated at 90°C overnight; ppt. was removed, soln. was evapd. in vac., residue was chromd. on silica;

DOI:10.1002/anie.200801958

Reference yield: 21.0%

1,2-dehydro-1,2-carborane (127065-16-1) + cyclohexene (110-83-8) → C2H11B10(C6H9) (127085-62-5)

Guidance literature:

1,2-dehydro-o-carborane is reacted with cyclohexene;

DOI:10.1021/ja00166a080

upstream raw materials:

1,2-dehydro-1,2-carborane

cyclohexene

bis(triphenylphosphine)nickel(II) chloride

n-butyllithium