CID 12622862

Base Information

Chemical Name:CID 12622862
CAS No.:75534-19-9
Molecular Formula:C₉H₁₀BrClO
Molecular Weight:249.535
Hs Code.:
DSSTox Substance ID:DTXSID401267942

Synonyms:75534-19-9;DTXSID401267942;1-Bromo-2-(2-chloroethyl)-4-methoxybenzene

Suppliers and Price of CID 12622862

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 0 raw suppliers

Chemical Property of CID 12622862

Chemical Property:

XLogP3:3.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:247.96036
Heavy Atom Count:12
Complexity:132

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC1=CC(=C(C=C1)Br)CCCl

Technology Process of CID 12622862

There total 4 articles about CID 12622862 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 75534-35-9
2-(2-bromo-5-methoxyphenyl)ethan-1-ol

: 75534-19-9
2-(2-bromo-5-methoxyphenyl)ethyl chloride

Guidance literature:: With tetrachloromethane; triphenylphosphine; at 84 ℃; for 14h;
DOI:10.1016/j.bmc.2008.06.047

Reference yield:

: 5020-41-7
2-(3-methoxyphenyl)-ethanol

: 75534-19-9
2-(2-bromo-5-methoxyphenyl)ethyl chloride

Guidance literature:: Multi-step reaction with 2 steps

1: 88 percent / bromine, pyridine / CH₂Cl₂ / 16 h / 25 °C

2: 77 percent / N,N-dimethylaniline, thionyl chloride / CHCl₃ / 12 h / Heating

With pyridine; thionyl chloride; bromine; N,N-dimethyl-aniline; In dichloromethane; chloroform;
DOI:10.1021/jo00314a026

Reference yield:

: 586-37-8
1-(3-Methoxyphenyl)ethanone

: 75534-19-9
2-(2-bromo-5-methoxyphenyl)ethyl chloride

Guidance literature:: Multi-step reaction with 3 steps

1: 73 percent / lithium aluminum hydride / tetrahydrofuran / 22 h / 25 °C

2: 88 percent / bromine, pyridine / CH₂Cl₂ / 16 h / 25 °C

3: 77 percent / N,N-dimethylaniline, thionyl chloride / CHCl₃ / 12 h / Heating

With pyridine; lithium aluminium tetrahydride; thionyl chloride; bromine; N,N-dimethyl-aniline; In tetrahydrofuran; dichloromethane; chloroform;
DOI:10.1021/jo00314a026